COMPOSITION, METHOD TO INCREASE THE FRAGRANCE PROFILE OF A COMPOSITION, METHOD TO PRODUCE A CONSUMER

专利摘要:
fragrance compositions. the present invention relates to a fragrance composition having improved fragrance profile intensity and / or longevity, comprising less than about 30% by weight of low volatility fragrance materials (i.e., base notes) having a pressure of steam <0.1 pa (0.001 torr) at 25 ° c, the weight% being in relation to the total weight of the fragrance component, and at least one form of the odorless fragrance modulator from an alkoxylated glycoside (eg methyl glucose ether ppg-20). the invention further relates to methods of using the compositions to perfume suitable substrates, including hard surfaces and body parts, especially skin and hair.
公开号:BR112016013533B1
申请号:R112016013533-4
申请日:2014-12-11
公开日:2020-12-15
发明作者:Christelle Marie Sandrine Bonnet；Lynette Anne Makins Holland；Fabienne PASTOR；Jose Maria Velazquez Mendoza；Jonathan Richard Stonehouse；William Eoghan Staite；David Thomas Stanton；Oreste Todini
申请人:The Procter & Gamble Company；
IPC主号:

专利说明:

FIELD OF THE INVENTION
[0001] The present invention relates to the field of perfumery. Specifically, the compositions of the present invention have enhanced fragrance profile intensity and / or longevity. BACKGROUND OF THE INVENTION
[0002] It has been a long tradition of highly skilled perfumers to carefully select fragrance materials to mix them into a composition in order to achieve a specific general fragrance profile of potency and character. In doing so, you must keep in mind the differences in character and individual volatility of the fragrance materials that are the components of the total fragrance. Conventional perfume compositions have a fragrance profile characterized by a high amount of low volatility fragrance materials and lower amounts of volatile fragrance materials. Low volatility fragrance materials are known as "base notes", while volatile fragrance materials can be further divided into high volatility fragrance materials, identified as "top or top notes" and medium fragrance materials. volatility, identified as "body or heart notes".
[0003] The starting notes tend to be citrus, herbal, smooth, refreshing, and typically comprise from about 0.1% by weight to 40% by weight relative to the total weight of the perfume formulation. The starting notes tend to evaporate quickly due to their high volatility and are characterized by a vapor pressure> 13 Pa (0.1 Torr) at 25 ° C (calculated using the Advanced Chemistry Development (ACD / Labs) V11.02 software ( © 1994-2013 ACD / Labs)). Typically, perfumers use starting notes to convey the initial impression of the composition, but they do not rely on them to contribute much to the total fragrance profile over time after application.
[0004] The body or heart notes make up from 0.1% by weight to about 40% by weight in relation to the total weight of the perfume formulation. They usually become dominant to the untrained nose several minutes after application and can last up to a few hours later. The body notes are associated with floral (for example, jasmine, rose), fruity, marine or spicy aromas and have an intermediate volatility in the vapor pressure in the range of 0.1 to 13 Pa (0.001 to 0.1 Torr) a 25 ° C.
[0005] The base or base notes can exist at> 30% by weight in relation to the total weight of the perfume formulation. They are characterized as animalic, woody, sweet, amber or musk, not being very volatile and having a vapor pressure <0.1 Pa (0.001 Torr) at 25 ° C. Typically, they are not perceived as dominant until several hours after the perfume is sprayed or during the "drying process". The base notes are essential to improve the intensity of the fragrance profile in general over time and replace the heart notes when they are in decline. The consequence of using base notes at high levels is that they transmit specific odor characters, such as musk, woody, amber, warm and sweet, which overcome and dominate the fragrance character over time. Some of these base notes have become so common materials (eg, hideous, galaxolid, etc.) that many fragrance drying looks repetitive, boring, not memorable and uninteresting to consumers. However, if the base notes are reduced or excluded, then the intensity of the fragrance weakens over time and does not last long enough.
[0006] Until today, due to the volatility of fragrance materials, the possible types of fragrance profiles or characters have been somewhat limited. A common complaint by consumers is that body notes tend to weaken very quickly after applying the composition and that the character of body notes is undesirably altered by the presence of large quantities of base notes during the period known as the "drying process"
[0007] Thus, it is desirable to have a composition that retains a significant portion of its initial fragrance character over time, consequently floral, fruity or spicy characters from the heart notes are perceived for many hours. It is also desirable that the fragrance intensity of the composition remains noticeable to the consumer for long periods of time. It is also desirable to have the ability to create fragrance profiles that are new to the world, in which one, or several, well-recognized heart note characters are maintained over time.
[0008] It is therefore a challenge to formulate a composition having improved fragrance character longevity, preferably components derived from volatile fragrance materials, without having the fragrance character substantially altered over time by the presence of base notes in the composition . One approach to overcome this challenge has been to formulate with higher proportions of perfume raw materials with low volatility and that are, therefore, more adherent to the substrate. However, as discussed above, this restricts the type of fragrance profile that can be achieved over time.
[0009] Another approach, as disclosed in US patent 4264478 (Amerchol Corp.), has been to use an odorless material, such as alkoxylated methyl glycoside, as a modulator to extend the longevity of perfume raw materials, which are normally too volatile to last a long time. However, US '478 patent simply teaches the addition of the modulator to an existing fragrance composition with a traditional construction of high levels of base note materials. Therefore, the total resulting effect on the fragrance profile of the composition would be to make the whole fragrance weaker due to the fact that the impact of the modulator on the more volatile fragrance materials cannot be observed due to the presence of excessive levels of the base notes. in the composition.
[0010] Similarly, Moshel, et al., Perfumer & Flavorist, Vol. 7, pages 41 to 47, 1982, teach that alkoxylated methyl glycosides work with a "fixative" and bind to individual perfume raw materials to improve the longevity of a specific perfume raw material. Moshel, et al. show that the fixative ability to improve longevity for any specific perfume raw material will depend on its boiling point. However, Moshel, et al. they do not reveal or suggest how to formulate an entire fragrance composition with the fixative, which incorporates multiple perfume raw materials, so that the intensity of the fragrance is maintained and the character of the body notes is perceived as dominant after many hours.
[0011] Therefore, the teachings of the prior art still have limitations and do not adequately teach how to provide a composition in which the prolonged fragrance profile is of sufficient intensity to be noticed and remain distinct in character over time. Therefore, there is a need for a composition that is perceived by the consumer over a long, preferably very long, duration after application. There is also a need for a composition that exhibits marked fragrance profile intensity over time, preferably so that volatile fragrance materials remain significantly consistent from their initial impression to the end. It is desirable that the compositions are relevant to fragrances derived from volatile fragrance materials with a vapor pressure> 0.1 Pa (0.001 Torr) at 25 ° C. SUMMARY OF THE INVENTION
[0012] In a first aspect, the present invention relates to a composition comprising a fragrance component present in the amount of about 0.04% by weight to about 30% by weight in relation to the total weight of the composition, and the fragrance component comprising at least one low volatility fragrance material with a vapor pressure <0.1 Pa (0.001 Torr) at 25 ° C, present in an amount of about 0.1% by weight at about 30% by weight, based on the total weight of the fragrance component, and at least one odorless fragrance modulator, preferably formed from an alkoxylated glycoside, present in the amount of about 0.1% by weight at about 20% by weight, based on the total weight of the composition.
[0013] In another aspect, the present invention relates to a composition in which the fragrance component additionally comprises one or more volatile fragrance materials having a vapor pressure> 0.1 Pa (0.001 Torr) at 25 ° C and present in an amount of about 70% by weight to about 99.9% by weight relative to the total weight of the fragrance component.
[0014] In yet another aspect, the present invention further relates to a method of modifying or improving the odor properties of a body surface with a composition of the present invention, by contacting or treating the body surface with the composition.
[0015] These and other additional features of the present invention will become apparent to the person skilled in the art when analyzing the detailed description below when taken in combination with the appended claims. BRIEF DESCRIPTION OF THE DRAWINGS
[0016] Although the descriptive report ends with claims that specifically mark and claim in a different way, it is believed that this will be better understood from the description below of the attached figures, in which:
[0017] Figure 1 provides the results of the panel test of the perceived fragrance profile, particularly the fragrance intensity, of the "Composition A" of the present invention comprising 8.00% by weight of low volatility fragrance materials compared to "Composition B", a negative control of a fragrance modulator (methyl glucose ether PPG-20), and as a function of the time elapsed since the application of the composition.
[0018] Figure 2 provides the results of the panel test of the perceived fragrance profile, particularly the fragrance character dominance, of the "Composition A" of the present invention comprising 8.00% by weight of low volatility fragrance materials if compared to "Composition B", a negative control of a fragrance modulator (methyl glucose ether PPG-20), and as a function of the time elapsed since the application of the composition.
[0019] Figure 3 provides the results of the panel test of the perceived fragrance profile, particularly the fragrance intensity, of "Composition C" of the present invention comprising 0.20% by weight of low volatility fragrance materials compared to "Composition D", a negative control of a fragrance modulator (methyl glucose ether PPG-20), and as a function of the time elapsed since the application of the composition.
[0020] Figure 4 provides the results of the panel test of the perceived fragrance profile, particularly differences in character of the fragrance, from "Composition C" of the present invention comprising 0.20% by weight of low volatility fragrance materials compared with "Composition D", a negative control of a fragrance modulator (methyl glucose ether PPG-20), and as a function of the time elapsed since the application of the composition.
[0021] Figure 5 provides the results of the panel test of the perceived fragrance profile, particularly the fragrance intensity, of the "Composition N" of the present invention comprising 54% by weight of low volatility fragrance materials compared to " Composition O ", a negative control of a fragrance modulator (methyl glucose ether PPG-20), and as a function of the time elapsed since the application of the composition.
[0022] Figure 6 provides the results of the panel test of the perceived fragrance profile, particularly of the fragrance character dominance, of the "Composition N" of the present invention comprising 54% by weight of low volatility fragrance materials compared to "Composition O", a negative control of a fragrance modulator (methyl glucose ether PPG-20), and as a function of the time elapsed since the application of the composition.
[0023] Figure 7 provides the results of the panel test of the perceived fragrance profile, particularly of the fragrance intensity, of "Composition I" in which the fragrance component comprises 40.14% by weight of low volatility fragrance materials if compared to "Composition J", a negative control of a fragrance modulator (methyl glucose ether PPG-20), and as a function of the time elapsed since the application of the composition.
[0024] Figure 8 provides the results of the panel test of the perceived fragrance profile, particularly of the fragrance intensity, of "Composition b" in which the fragrance component comprises 1.0% by weight of low volatility fragrance materials if compared to "Composition a", a negative control of a fragrance modulator (Simulsol SL11W ™), and as a function of the time elapsed since the application of the composition.
[0025] Figure 9 provides the results of the panel test of the perceived fragrance profile, particularly of the fragrance intensity, of "Composition d" in which the fragrance component comprises 1.0% by weight of low volatility fragrance materials if compared to "Composition c", a negative control of a fragrance modulator (Plantacare® 810 UP), and as a function of the time elapsed since the application of the composition. DETAILED DESCRIPTION OF THE INVENTION Definitions
[0026] As used herein, articles such as "one" and "one", when used in a claim, are understood to mean one, or more than one, of what is claimed or described.
[0027] As used here, the terms "include", "includes" and "including" are intended to be non-limiting.
[0028] As used here, the term "composition" includes a fine fragrance composition intended for application to a body surface, such as, for example, skin or hair, that is, to impart a pleasant odor to them or to disguise a bad smell ourselves. They are generally in the form of perfume concentrates, perfumes, eau de parfums, eau de toilettes, aftershave lotions, colognes, scented waters or body sprays. Fine fragrance compositions can be ethanol-based compositions. The term "composition" also includes a cosmetic composition, which comprises a fragrance material for the purpose of releasing a pleasant smell to induce consumer acceptance of the cosmetic composition. The term "composition" also includes cleaning compositions, such as fabric care compositions or home care compositions, including air care compositions, for use on clothing or other substrates such as hard surfaces (for example, dishes, floors and counter surfaces). Additional non-limiting examples of "composition" may also include facial or body powder, foundation, body / facial oil, mousse, creams (for example, cold creams), waxes, filters and sunscreens, shower gels, lip balms, compositions for self-tanning, masks and plasters.
[0029] As used here, the term "consumer" means the user of the compositions and the observer near or around the user.
[0030] As used here, the term "fragrance material" and "fragrance materials" refer to a perfume raw material or mixture of perfume raw material, which are used to impart an odor or fragrance profile generally pleasant to a composition. "Fragrance materials" may include any perfume raw materials suitable for fragrance uses, including materials such as, for example, alcohols, aldehydes, ketones, esters, ethers, acetates, nitriles, terpene hydrocarbons, sulfurous and nitrogenous heterocyclic compounds and essencial oils. However, naturally occurring vegetable and animal oils and exudates that contain complex mixtures of various chemical components are known for use as "fragrance materials". The individual perfume raw materials that comprise a known natural oil can be found by reference to magazines commonly used by those skilled in the art such as "Perfume and Flavor" or "Journal of Essential Oil Research", or listed in reference texts such as the book by S. Arctander, Perfume and Flavor Chemicals, 1969, Montclair, New Jersey, USA and most recently republished by Allured Publishing Corporation Illinois (1994). In addition, some perfume raw materials are supplied by fragrance houses (Firmenich, International Flavors & Fragrances, Givaudan, Symrise) as mixtures in the form of special properties chords. Non-limiting examples of fragrance materials used herein include pro-fragrances such as acetal pro-fragrances, ketal pro-fragrances, ester pro-fragrances, hydrolyzable organic and inorganic pro-fragrances and mixtures thereof. Fragrance materials can be released from pro-fragrances in a variety of ways. For example, the fragrance can be released as a result of simple hydrolysis or by a change in an equilibrium reaction or by a change in pH or by enzymatic release.
[0031] As used here, the term "fragrance profile" means the description of how the fragrance perceived by the human nose evolves over time from when it is first applied. It is the result of the combination of the starting notes, body and base, if present, of a fragrance. The fragrance profile is comprised of two characteristics: "Intensity" and "character". The "intensity" refers to the perceived potency while the "character" refers to the olfactory impression or the quality of the perfume, that is, fruity, floral, woody, etc.
[0032] As used here, the terms "perfume" and "fragrance" are used interchangeably to designate the component in the composition that is formed of fragrance materials, that is, ingredients capable of conferring or modifying the odor of the skin or skin. hair or other substrate.
[0033] As used here, the terms "modulator" and "fixative" are used interchangeably to designate an agent capable of affecting the fragrance profile by impacting the evaporation rate of fragrance materials. When incorporating the modulator, it is desirable that the fragrance profile, preferably the components of the volatile fragrance materials of the composition, can be perceived by an observer or user of it, for a longer period of time, if compared to the same perception in the absence of the modulator. In particular, according to the invention, the alkoxylated glycoside, preferably the methyl glucose ether PPG-20 (Glucam ™ P-20, available from Lubrizol (USA)), is a modulator of the perceived toughness of the compositions of the present invention, that is, it is used to prolong the perceived intensity of the fragrance profile over time, compared to the perception when the PPG-20 methyl glucose ether is not used in the composition. However, as discovered by the inventors, simply adding modulators to the traditionally manufactured fragrance composition will not ensure an improved or improved fragrance profile over time. Instead, it is only when modulators are added in the presence of reduced levels of low volatility fragrance materials that the intensity of the fragrance profile, preferably volatile fragrance materials, can be perceived for long periods compared to compositions of control without modulators and low levels of low volatility fragrance materials.
[0034] As used here, the term "commoditizer" means an agent that is added to the composition in addition to modulators and has the similar function of impacting the evaporation speed and intensity of fragrance materials, in order to improve or prolong perception fragrance profile by the consumer. A preferred example of a commoditizer is isocetyl alcohol (CERAPHYL® ICA; see PCT patent publication No. WO2013 / 64412 (Firmenich)).
[0035] As used herein, the term "odorless" means an agent that does not impart its own odor when added to a composition of the present invention. For example, an "odorless modulator" such as methyl glucose ether PPG-20 does not impart a new odor that alters the character of the composition to which it is added.
[0036] As used here, the term "vapor pressure" means the partial pressure in the air at a defined temperature for given chemical species. It defines a chemical species' desire to be in the gas phase rather than in the liquid or solid state. The lighter the vapor pressure, the greater the proportion of the material that will, in equilibrium, be found in a closed headspace. It is also related to the rate of evaporation of a fragrance material that is defined in an open environment where the material leaves the system. The vapor pressure is determined according to the Advanced Chemistry Development (ACD / Labs) reference program, Software Version 11.02, (© 1994-2013).
[0037] It should be understood that the test methods presented in the Test Methods section of the present application need to be used to determine the respective values of the Applicants' inventive parameters as described and claimed in the present invention.
[0038] In all embodiments of the present invention, all percentages are by weight of the total composition, as is evident from the context, except where otherwise specified. All ratios are ratios between weight, unless otherwise specified, and all measurements are made at 25 ° C, unless otherwise specified. Compositions:
[0039] Specifically, in one aspect, the present invention provides a composition comprising a fragrance component present in an amount of about 0.04% by weight to 30% by weight, preferably 1% by weight to about 30% by weight, preferably less than 25% by weight, preferably less than 20% by weight, preferably less than 15% by weight, preferably less than about 10% by weight or preferably less than 8% by weight, in relation to the total weight of the composition. Alternatively, the fragrance component is present in an amount of about 0.04% by weight, 0.3% by weight, 1% by weight, 8% by weight or 10% by weight, at about 15% by weight , 20% by weight, 25% by weight or 30% by weight, based on the total weight of the composition.
[0040] In addition, the fragrance component comprises at least one fragrance material of low volatility having a vapor pressure <0.1 Pa (0.001 Torr) at 25 ° C. In certain embodiments, the compositions of the present invention comprise at least 5 low volatility fragrance materials. It is preferable that the composition of the present invention comprises low, preferably very low, or even negligible levels of the low volatility fragrance materials that would traditionally be present in a composition. Accordingly, the compositions of the present invention may comprise low levels of the volatile fragrance material present in an amount of about 0.01% by weight to about 30% by weight, preferably less than 25% by weight, preferably less than 20% by weight, preferably less than 12% by weight, preferably less than about 10% by weight or preferably less than about 8% by weight, preferably less than about 5% by weight, preferably less than about 1% by weight, or combinations thereof, in relation to the total weight of the fragrance component. Alternatively, the low volatility fragrance material is present in an amount of about 0.01% by weight, 1% by weight, 2% by weight, 5% by weight, 8% by weight, 10% by weight, 12 % by weight, 15% by weight, 20% by weight, 25% by weight or 30% by weight, based on the total weight of the fragrance component. If there is more than one low volatility fragrance material, then the ranges provided here above cover the total of all low volatility fragrance materials.
[0041] The composition additionally comprises, at least, an odorless fragrance modulator formed from an alkoxylated glycoside, preferably selected from the group consisting of polyglycoside polyol, ethyl glycolide polyol and propyl glycoside polyol, in which the alkoxylated glycoside it is preferably PPG-20 methyl glycoside ether (GLUCAM ™ P-20 available from Lubrizol, USA). The alkoxylated glycoside is present in an amount of about 0.1% by weight to about 20% by weight, preferably from about 0.5% by weight to about 18% by weight or more preferably about 2 , 5% by weight to about 15% by weight, or combinations thereof, with respect to the total weight of the composition. Alternatively, the alkoxylated glycoside is present in an amount of about 0.1 wt%, 0.5 wt%, or 2.5 wt% to about 15 wt%, 18 wt% or 20 wt% weight in relation to the total weight of the composition. If there is more than one odorless fragrance modeler, then the ranges provided here above cover the total of all odorless fragrance modulators.
[0042] In one embodiment, the odorless modulator of the present invention is preferably a liquid at temperatures below 100 ° C, preferably at room temperature. Particularly, the preferred odorless modulators are completely miscible with PRMs (perfume raw materials) to form a single phase liquid. However, if PRMs are not fully miscible, or are immiscible, then co-solvents (eg, dipropylene glycol (DPG), triethyl citrate, or others also known to those skilled in the art) can be added to aid in the solubility of PRMs.
[0043] The inventors surprisingly found that by reducing the levels of low volatility fragrance materials (eg base notes) in the composition, the effect of odorless modulators on the fragrance profile, particularly the portion of the fragrance profile that is derived from volatile fragrance materials (ie, starting and body notes), can be improved. "Enhanced" means that the fragrance character of the composition, in particular the components that contribute to volatile fragrance materials, can be perceived by the consumer at later points in time, such as 2 hours, 4 hours, 6 hours , 8 hours, 10 hours and possibly all the time up to 24 hours after application in comparison to controls, that is, compositions containing normal or large levels of low volatility fragrance materials and the odorless modulator, or compositions containing reduced levels fragrance materials with low volatility and no odor-free modulator.
[0044] Alternatively, "improved" may mean that the perception of components contributed by volatile fragrance materials, by the consumer, is markedly increased or improved when compared to controls. "Increased" or "heightened" perception of the fragrance profile means that the consumer perceives the fragrance profile of an unmodified composition from the initial impression or the modifications are minimal from when the composition was first applied to when it dissipated.
[0045] Typically, it was very difficult to formulate the fragrance profile with a chord, particularly a floral chord characteristic of the body notes, which can last for very long periods, especially throughout the life of the composition after application, without hiding the stronger odors from the base notes. The present invention of reduced levels of low volatility fragrance materials (ie base notes) with modulators will allow perfumers to increase the perception of volatile perfume materials, particularly body notes, to create new characters and address a recurrent consumer problem that specific fragrance profiles, particularly floral scents, do not last long enough.
[0046] Such a solution as presented here provides marked fragrance profile longevity, particularly among those compositions formulated from volatile fragrance materials having medium to high vapor pressure ranges (> 0.1 Pa (0.001 Torr) at 25 ° C), without having to depend on the presence or significant quantities of volatile fragrance materials, which tend to dominate and alter the character of a fragrance. This provides the perfumer with options to formulate chords with new fragrance profiles.
[0047] In another aspect, the present invention also provides a composition, wherein the fragrance component further comprises one or more volatile fragrance materials having a vapor pressure> 0.1 Pa (0.001 Torr) at 25 ° C. The volatile fragrance material is present in an amount of about 70% by weight to about 99.9% by weight, preferably greater than about 80% by weight, or most preferably greater than 88% by weight, or combinations thereof, in relation to the total weight of the fragrance component. Alternatively, the volatile fragrance material is present in an amount of about 70% by weight, 80% by weight, 85% by weight, 88% by weight, 90% by weight, 95% by weight, 98% by weight or 99.9% by weight, based on the total weight of the fragrance component. In certain embodiments, the compositions of the present invention comprise at least 5, at least 10, at least 15, at least 20 volatile fragrance materials. If there is more than one volatile fragrance material, then the bands provided here above cover the total weight of all volatile fragrance materials.
[0048] In one embodiment, volatile fragrance materials can be divided into two: (i) a highly volatile fragrance material having a vapor pressure> 13 Pa (0.1 Torr) at 25 ° C, and (ii ) a medium volatility fragrance material having a vapor pressure in the range of 0.1 Pa at 25 ° C to 13 Pa at 25 ° C (0.001 Torr at 25 ° C to 0.1 Torr at 25 ° C). While the additional classification of volatile fragrance materials into high volatility and medium fragrance materials is provided to help illustrate the fragrance characters of the perfume raw materials and is useful when it comes to formulating new fragrance profiles, it should not be considered as a limitation on what qualifies as a volatile fragrance material.
[0049] In yet another aspect, the low volatility fragrance material is preferably selected from the ingredients shown in Table 1 below.
[0050] In yet another aspect, the present invention also provides a composition further comprising one or more odorless fragrance comodulators selected from the group consisting of: (i) Isocetyl alcohol (CERAPHYL® ICA); (ii) PPG-3 myristyl ether (preferably Tegosoft ™ APM and / or Varonic® APM); (iii) Neopentyl glycol diethylhexanoate (preferably Schercemol ™ NGDO); and (iv) mixing them, preferably, with isocetyl alcohol (CERAPHYL® ICA); Where fragrance commodifiers are present in an amount of about 0.05% by weight to about 10% by weight, preferably from about 0.5% by weight to about 6% by weight, or combinations thereof , in relation to the total weight of the composition. Alternatively, fragrance commodifiers are present in an amount of about 0.05% by weight or 0.5% by weight to about 6% by weight or 10% by weight, based on the total weight of the composition. If there is more than one odorless fragrance commoditizer, then the ranges provided here above cover the total of all odorless fragrance commoditizers.
[0051] In one embodiment, odorless fragrance modulators are made up of at least 50% by weight of an odorless fragrance modulator, relative to the total weight of odorless modulators and odorless commododulators present in the composition.
[0052] In yet another aspect, the present invention provides a composition comprising: (i) from about 50% by weight to about 80% by weight of ethanol; (ii) from about 0.1% by weight to about 20% by weight of at least one odorless fragrance modulator formed by an alkoxylated glycoside selected from the group consisting of methyl glycol polyol, ethyl glycol polyol and propyl glycol polyol , preferably methyl glucose ether PPG-20; and (iii) a fragrance component; and wherein the% by weight of the odorless fragrance modulator is greater than that of the fragrance component. Imprisonment materials
[0053] In yet another aspect, the compositions of the present invention can comprise a trapping material at a level such that the ratio between the weight of the trapping material and the weight of the fragrance materials is in the range of about 1: 20 to about 20: 1. Preferably, the composition may comprise a trapping material present in the amount of about 0.001% by weight to about 40% by weight, from about 0.1% by weight to about 25% by weight, from about 0 , 3% by weight to about 20% by weight, from about 0.5% by weight to about 10% by weight, or from about 0.75% by weight to about 5% by weight, with respect to the total weight of the composition. The composition disclosed in the present invention can comprise from 0.001% by weight to 40% by weight, from 0.1% by weight to 25% by weight, from 0.3% by weight to 20% by weight, from 0.5% by weight to 10% by weight or from 0.75% by weight to 5% by weight, based on the total weight of the composition of a cyclic oligosaccharide.
[0054] Binding materials suitable for use in the present invention are selected from polymers; capsules, microcapsules and nanocapsules; liposomes, absorbents; cyclic oligosaccharides and their mixtures. Cyclic absorbents and oligosaccharides and mixtures thereof are preferred. Highly preferred are cyclic oligosaccharides (see PCT publication Nos. WO2000 / 67721 (Procter &Gamble); and WO2000 / 67720 (Procter &Gamble); and US patent No. 6,893,647 (Procter & Gamble)).
[0055] As used herein, the term "cyclic oligosaccharide" means a cyclic structure comprising six or more units of saccharide. Preferred, for use in the present invention, cyclic oligosaccharides with six, seven or eight units of saccharide and a mixture thereof, more preferably six or seven units of saccharide and most preferably seven units of saccharide. It is common in the art to abbreviate cyclic oligosaccharides of six, seven and eight members to α, β and y, respectively.
[0056] The cyclic oligosaccharide of the compositions used for the present invention can comprise any suitable saccharide or mixtures of saccharides. Examples of suitable saccharides include, but are not limited to, glucose, fructose, mannose, galactose, maltose and mixtures thereof. However, cyclic oligosaccharides or glucose are preferred for use in the present invention. The preferred cyclic oligosaccharides for use in the present invention are α-cyclodextrins or β-cyclodextrins or mixtures thereof, and the most preferred cyclic oligosaccharides for use here are β-cyclodextrins.
[0057] Cyclic oligosaccharides or mixtures of cyclic oligosaccharides, for use in the present invention, can be replaced by any suitable substituent or mixture of the substituents. Here the use of the term "mixture of substituents" means that two or more suitable different substituents can be substituted for a cyclic oligosaccharide. Most cyclodextrin derivatives consist of molecules in which some of the OH groups have been replaced. Suitable substituents include, but are not limited to, alkyl groups; hydroxy alkyl groups; dihydroxy alkyl groups; bridging groups (hydroxy alkyl) alkenyl such as cyclodextrin glycerol ethers; aryl groups; maltose groups; allyl groups; benzyl groups; alkanoyl groups; cationic cyclodextrins such as those containing 2-hydroxy-3- (dimethylamino) propyl ether; quaternary ammonium groups; anionic cyclodextrins such as carboxyalkyl groups, sulfobutyl ether groups, sulfate groups and succinylates; amphoteric cyclodextrins; and mixtures thereof.
[0058] Substituents can be saturated or unsaturated, straight chain or branched. Preferred substituents include saturated and straight chain alkyl groups, hydroxy-alkyl groups and mixtures thereof. The alkyl and hydroxy alkyl substituents are selected from C1-C8 alkyl or hydroxy alkyl groups or mixtures thereof, more preferably alkyl and hydroxy alkyl substituents are selected from the C1-C6 alkyl or hydroxy alkyl groups or mixtures thereof, more preferably furthermore the alkyl and hydroxy alkyl substituents are selected from alkyl or hydroxy C1-C4 alkyl groups and mixtures thereof. Especially preferred alkyl and hydroxy alkyl substituents are propyl, ethyl and methyl, more especially propyl and methyl hydroxy and more preferably methyl.
[0059] The preferred cyclic oligosaccharides for use in the present invention are substituted or unsubstituted by only alkyl or hydroxy alkyl saturated straight chain substituents. Therefore, preferred examples of cyclic oligosaccharides for use in the present invention are α-cyclodextrin, β-cyclodextrin, methyl-α-cyclodextrin, methyl-β-cyclodextrin, hydroxy propyl-α-cyclodextrin and hydroxy propyl-β-cyclodextrin. Most preferred examples of cyclic oligosaccharides for use in the present invention are methyl-α-cyclodextrin and methyl-β-cyclodextrin. These are available from Wacker-Chemie GmbH Hanns-Seidel-Platz 4, Munich, Germany under the trade name Alpha W6 M and Beta W7 M, respectively. Methyl-β-cyclodextrin is especially preferred.
[0060] The cyclic oligosaccharides of the compositions used for the present invention are preferably soluble in water, ethanol or in both water and ethanol. As used herein, "soluble" means at least about 0.1 g of solute dissolved in 100 ml of solvent at 25 ° C and 0.1 MPa (1 atm) pressure. Preferably, the cyclic oligosaccharides for use in the present invention have a solubility of at least about 1 g / 100 ml at 25 ° C and 0.1 MPa (1 atm) pressure. Preferably cyclic oligosaccharides are only present at levels up to their solubility limits in a given composition at room temperature. The person skilled in the art will recognize that the levels of cyclic oligosaccharides used in the present invention will also be dependent on components of the composition and their levels, for example, the solvents used or the exact fragrance oils, or combination of fragrance oils, present in the composition . Therefore, although the limits set for the trap material are preferred, they are not exhaustive. Volatile solvents
[0061] In yet another aspect, the present invention provides the solution to the problem of extending the longevity of the fragrance profile of the compositions, particularly fine fragrances and cosmetic compositions, preferably fine fragrance compositions, which generally contain high levels of ethanol and other alcohols (for example, methanol, propanol, isopropanol, butanol and mixtures thereof) normally found in commercially fragrance products. Consequently, ethanol can be present in any of the compositions of the present invention, and more specifically it will form from about 10% by weight to about 80% by weight, or even from about 25% by weight to about 75% by weight of the composition, or combinations thereof, in relation to the total weight of the composition. Alternatively, ethanol can be present in an amount of about 10% by weight or 25% by weight to about 75% by weight or 80% by weight, based on the total weight of the composition. Any acceptable ethanol quality, compatible and safe for the specific intended use of the composition, for example, topical applications of fine fragrances or cosmetic compositions, is suitable for use in the compositions according to the present invention. Non-volatile solvents
[0062] The composition may comprise a non-volatile solvent or a mixture of non-volatile solvents. Non-limiting examples of non-volatile solvents include benzyl benzoate, diethyl phthalate, isopropyl myristate, propylene glycol, dipropylene glycol, triethyl citrate, and mixtures thereof. These solvents are often introduced to the product through the perfume oil since many raw materials of the perfume can be purchased as a dilution in one of these solvents. Where non-volatile solvents are present, introduced with the perfume materials or separately, then, for the purpose of calculating the proportion of the fragrance component having a vapor pressure of <0.1 Pa (0.001 Torr) at 25 ° C, the total fragrance components do not include non-volatile solvents. In addition, if present with cyclic oligosaccharides, the non-volatile solvent may be included in a ratio of less than 1: 1, less than 1: 2, less than 1:10, to the cyclic oligosaccharide less than 1: 100. Water
[0063] In another aspect, water can be present in any of the compositions of the present invention, and more specifically, it should not exceed about 40% by weight, preferably about 20% by weight or less, or more preferably about 10% by weight, based on the total weight of the composition. Alternatively, the water can be present in an amount of about 10% by weight or 20% by weight to about 40% by weight, based on the total weight of the composition. When the composition is a cosmetic composition, the water level should not be so high that the product does not become cloudy, thus negatively impacting the aesthetics of the product. It is understood that the amount of water present in the composition may be that of the water present in the ethanol used in the composition, as may be the case. Propellants
[0064] The compositions described herein may include a propellant. Some examples of propellants include compressed air, nitrogen, inert gases, carbon dioxide and mixtures thereof. Propellants can also include gaseous hydrocarbons such as propane, n-butane, isobutene, cyclopropane and mixtures thereof. Halogenated hydrocarbons, such as 1,1-difluoroethane, can also be used as propellants. Some non-limiting examples of propellants include 1,1,1,2,2-pentafluoroethane, 1,1,1,2-tetrafluoroethane, 1,1,1,2,3,3,3-heptafluoropropane, trans-1,3 , 3,3-tetrafluoroprop-1-ene, dimethyl ether, dichlorodifluoromethane (propellant 12), 1,1-dichloro-1,1,2,2-tetrafluoroethane (propellant 114), 1-chloro-1,1-difluoro- 2,2-trifluoroethane (propellant 115), 1-chloro-1,1-difluoroethylene (propellant 142B), 1,1-difluoroethane (propellant 152A), monochlorodifluoromethane, and mixture thereof. Some other propellants suitable for use include, but are not limited to, A-46 (a mixture of isobutane, butane and propane), A-31 (isobutane), A-17 (n-butane), A-108 (propane) , AP70 (a mixture of propane, isobutane and n-butane), AP40 (a mixture of propane, isobutene and n-butane), AP30 (a mixture of propane, isobutane and n-butane) and 152A (1,1 difluoro ethane ). The propellant can have a concentration of about 15%, 25%, 30% 32%, 34%, 35%, 36%, 37% 38%, 40% or 42% to about 70%, 65%, 60% , 54%, 52%, 50%, 48%, 46%, 44% or 42% by weight of the total filling of the materials stored inside the device. Antiperspirant Active Principle
[0065] The compositions described herein may be free of, substantially free of, or may include an antiperspirant active (i.e., any substance, mixture or other material having antiperspirant activity). Examples of antiperspirant actives include astringent metallic salts, such as inorganic and organic salts of aluminum, zirconium and zinc, as well as mixtures thereof. Such antiperspirant actives include, for example, aluminum and zincium salts, such as aluminum halides, aluminum hydroxide halides, zirconyl oxyhalides, zirconyl hydroxide halides and mixtures thereof. Other ingredients
[0066] In yet another aspect, the composition consists essentially of the listed ingredients, but may contain small amounts (no more than about 10% by weight, preferably no more than 5% by weight, or preferably no more than 2% in weight of them, in relation to the total weight of the composition) of other ingredients that do not impact the fragrance profile, particularly the speed of evaporation and release of fragrance materials. For example, a fine fragrance composition may comprise stabilizing or antioxidant agents, UV filters or extinguishers, or coloring agents, commonly used in perfumery. There are a number of other examples of additional ingredients that are suitable for inclusion in the present compositions, particularly in compositions for cosmetic use. These include, but are not limited to, alcohol denaturants such as denatonium benzoate; UV stabilizers like benzophenone-2; antioxidants such as tocopheryl acetate; preservatives such as phenoxy ethanol, benzyl alcohol, methyl paraben and propyl paraben; dyes, pH adjusting agents, such as lactic acid, citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide and sodium carbonate; deodorants and antimicrobials such as farnesol and zinc phenolsulfate; humectants like glycerin; oils; skin conditioning agent such as allantoin; cooling agent such as trimethyl isopropyl butanamide and menthol; conditioning ingredient for hair such as panthenol, pantethine, pantothin, panthenyl ethyl ether and combinations thereof. silicones; solvents such as hexylene glycol; hair-fixing polymers as described in PCT publication WO94 / 08557 (Procter &Gamble); salts in general, such as potassium acetate and sodium chloride and mixtures thereof;
[0067] In another aspect, the composition of the present invention, depending on its intended use, is a mixture of fragrance materials possibly together with other ingredients, such as, for example, perfume vehicles. The term "perfume vehicle" is intended to include materials that are practically neutral from a perfumery point of view, that is, that does not significantly alter the organoleptic properties of the perfuming components. The perfume vehicle can be compatible liquid and solid fillers, thinners, extenders and the like. The term "compatible", as used here, means that the components of the composition of the present invention are capable of mixing with the primary active principle of the present invention, as well as with each other, in a way that there is no interaction that can substantially reduce the effectiveness of the composition, under normal use situations. The type of vehicle used in the present invention depends on the type of product desired and may comprise, but is not limited to, solutions, aerosols, emulsions (including oil in water and water in oil), gels and liposomes. Preferably, the carrier is a liquid and will be a solvent, such as, for example, dipropylene glycol, diethyl phthalate, isopropyl myristate, benzyl benzoate, 2- (2-ethoxy ethoxy) -1- ethanol or ethyl citrate (citrate triethyl).
[0068] In yet another aspect, the compositions for use in the present invention can take any form suitable for use, more preferably for cosmetic or perfumery use. These include, but are not limited to, spray sprays, aerosols, emulsions, lotions, liquids, creams, gels, sticks, ointments, mousses, powders, granulated products, substrates, cosmetics (for example, semi-solid or liquid make-up, including bases ) and the like. Preferably, the compositions for use in the present invention take the form of a spray of steam. The compositions of the present invention can also be included as an ingredient in other compositions, preferably cosmetic and fine fragrance compositions, in which they are compatible. Therefore, they can be used in solid compositions or applied substrates, etc.
[0069] It has been found that among such compositions of the present invention, the preferred compositions are those comprising: (i) a fragrance component present in the amount of about 1.0% by weight to about 30% by weight in relation to total weight of the composition, and where the fragrance component comprises: (a) at least one fragrance material of low volatility having a vapor pressure <0.1 Pa (0.001 Torr) at 25 ° C, present in the amount of about from 0.1% by weight to about 30% by weight, preferably less than about 28% by weight, preferably less than about 25% by weight, preferably less than about 22% by weight, preferably less than about 20% by weight, preferably less than about 18% by weight or preferably less than about 15% by weight, relative to the total weight of the fragrance component; and (b) at least one volatile fragrance material having a vapor pressure> 0.1 Pa (0.001 Torr) at 25 ° C, present in an amount of about 70% by weight to about 99.9% by weight , in relation to the total weight of the fragrance component; and (ii) at least one odorless fragrance modulator formed from an alkoxylated glycoside, preferably PPG-20 methyl glucose ether, in the amount of about 2.5% by weight to about 20% by weight, based on weight total composition.
[0070] In one embodiment, the composition additionally comprises one or more odorless fragrance comodulators selected from the group consisting of isocetyl alcohol, (CERAPHYL® ICA), myristyl ether PPG-3 (preferably Tegosoft ™ APM and / or Varonic® APM), neopentyl glycol diethylexanoate (preferably Schercemol ™ NGDO), and mixtures thereof, preferably with isocetyl alcohol (CERAPHYL® ICA), present in the amount of about 0.5% by weight to about 10% by weight, in relation to the total weight of the composition.
[0071] Therefore, it need not be said that the compositions of the present invention encompass any composition comprising any ingredient cited herein, in any embodiment, wherein each said ingredient is independently present in any appropriate amount as defined herein. Many of the aforementioned compositions, of which are specifically established here, can be covered. Manufacturing item
[0072] The composition can be included in a manufacturing article comprising a spray applicator. The spray applicator may comprise a container for containing the composition to be dispensed. The spray applicator may comprise an aerosolizing composition (i.e., a composition containing a propellant) also within the container. Other non-limiting examples of spray applicators include non-aerosol applicators (e.g., steam sprays), manually activated applicators, spray pump applicators, or any other suitable spray applicators available in the art. Method of using the composition
[0073] The composition of the present invention according to any of the modalities described here is a useful perfumery composition, which can be advantageously used as consumer products intended to perfume any suitable substrate. As used herein, the term "substrate" means any surface to which the composition of the present invention can be applied without causing any undue adverse effects. For example, this can include a wide range of surfaces including human or animal skin, paper (scented paper), air in an environment (air purifier or aromatherapy composition), fabric, furniture, crockery, hard surfaces and related materials . Preferred substrates include body surfaces such as hair and skin, with skin being the most preferred.
[0074] The composition of the present invention can be used in a conventional manner to scent a substrate. An effective amount of the composition, typically from about 1 μl to about 10,000 μl, preferably from about 10 μl to about 1,000 μl, more preferably from about 25 μl to about 500 μl, or most preferably from about 50 μl to about 100 μl, or combinations thereof, is applied to the appropriate substrate. Alternatively, an effective amount of the composition of the present invention is about 1 μl, 10 μl, 25 μl or 50 μl to about 100 μl, 500 μl, 1,000 μl or 10,000 μl. The composition can be applied manually or using an application apparatus, such as a vaporizer or atomizer. Preferably, the composition is left to rest after application to the substrate. The scope of the present invention should be considered to cover one or more applications other than the composition or the continuous release of a composition through a vaporizer or other type of atomizer.
[0075] In one embodiment, the present invention preferably relates to fine fragrance compositions in the form of perfume, eau de toilette, eau de parfum, cologne, perfumed water or a body spray. Therefore, in accordance with this embodiment, the present invention provides a method for modifying or improving the odor properties of a body surface, preferably hair or skin, comprising contacting or treating the body surface with a composition of the present invention.
[0076] In another embodiment, the present invention relates to compositions of the present invention that can be used as products or consumer items selected from the group consisting of a tissue treatment product, an air treatment product or a environmental treatment product. Therefore, according to this modality, the present invention provides a method for modifying or improving the odor properties of a body surface, preferably fabric, furniture, tableware, hard surfaces and related materials, comprising contacting or treating the substrate with a composition of the present invention.
[0077] In another aspect, the present invention is directed to a method for enhancing the fragrance profile of a composition, preferably by improving the longevity of an aroma in the composition. The method comprises contacting or mixing at least one odorless fragrance modulator with at least one low volatility fragrance material according to the composition of the present invention. Preferably, the aroma is derived from volatile fragrance materials in the composition and is characterized by a floral aroma. Non-limiting examples of floral aroma include notes of lavender, notes of rose, notes of lily-of-the-valley, notes of muguet, notes of jasmine, notes of magnolia, notes of cyclamen, notes of hyacinth, notes of lilac, notes of orange flowers, cherry blossom notes, peony notes, lotus notes, linden notes, osmanthus notes, heliotrope notes, violet notes, orris root notes, tiaré notes and the like.
[0078] In one embodiment, the fragrance or aroma profile of the composition is detectable by a consumer at later times, for example, 2 hours, 4 hours, 6 hours, 8 hours, 10 hours and possibly up to 24 hours after application composition on a substrate compared to controls. Fragrance materials
[0079] In order that the compositions can be developed with the appropriate fragrance profile for the present invention, the "fragrance materials" have been classified by their vapor pressure, as determined according to the Advanced Chemistry Development reference program ( ACD / Labs), Software Version 11.02, (1994 2013). For the sake of clarity, when fragrance materials refer to an individual composition, their vapor pressure must be determined according to the reference program mentioned above. In the case where the fragrance materials are natural oils, extracts or absolutes, which comprise a mixture of several compounds, the vapor pressure of the complete oil must be treated as a mixture of individual perfume raw material components using the program mentioned above. The individual components and their levels, in any natural oil or extract, can be determined by direct injection of the oil into a GC-MS column (gas chromatography with mass spectrometer) for analysis as known to one skilled in the art. In the scenario where the fragrance materials are a proprietary specialty chord, so called "bases", the vapor pressure, using the reference program mentioned above, must be obtained from the supplier. However, it is understood by one skilled in the art that he can physically analyze the composition of a commercially available complete fragrance oil to identify fragrance raw materials and their levels using standard GC-MS techniques. This would be independent of whether they were added to the fragrance oil as individual chemicals, as components of natural bases or proprietary bases. Although proprietary and natural bases are included in the examples, when analyzing a commercially available fragrance through GC-MS, a person could simply identify the components of the base or natural oil as part of a total fragrance blend and its levels, without being able to identify from which proprietary base or natural oil the fragrance originated.
[0080] The nature and type of fragrance materials in the compositions according to the present invention can be selected by the person skilled in the art, based on his general knowledge together with the teachings contained here, with reference to the intended use or application of the composition and the effect of the desired fragrance profile. Examples of suitable fragrance materials are disclosed in US Patent No. 4,145,184, US Patent No. 4,209,417, US Patent No. 4,515,705 and US Patent No. 4,152,272, provided that the composition comprises volatile fragrance materials. suitable in levels in an amount of about 0.1 wt% to about 30 wt%, preferably less than about 28 wt%, preferably less than about 25 wt%, preferably less than about of 22% by weight, preferably less than 20% by weight, preferably less than 18% by weight, or preferably less than 15% by weight, or combinations thereof, in relation to the total weight of the fragrance component.
[0081] Examples of fragrance materials having a vapor pressure <0.1 Pa (0.001 Torr) at 25 ° C (according to the Advanced Chemistry Development (ACD / Labs) reference program, Software Version 11.02, (© 1994-2013)) to form a maximum of about 30% by weight of volatile fragrance materials as shown in Table 1 below.













[0082] In one embodiment, the compositions of the present invention are those among low volatility fragrance materials that comprise at most about 30% by weight, preferably at most about 28% by weight, preferably at most about 25% by weight, preferably at most about 22% by weight, preferably at most about 20% by weight, preferably at most about 18% by weight, preferably at most about 15% by weight, or alternatively their combinations, in relation to the total weight of the fragrance component. Examples of low volatility fragrance materials selected from the group consisting of the ingredients mentioned in Table 1 are preferred. However, it is understood by one skilled in the art that other low volatility fragrance materials, not listed in Table 1, are also within the scope. scope of the present invention, as long as they have a vapor pressure ˂ 0.1 Pa (0.001 Torr) at 25 ° C.
[0083] In another aspect, the compositions of the present invention additionally comprise one or more volatile fragrance materials having a vapor pressure ≥ 0.1 Pa (0.001 Torr) at 25 ° C (according to the Software Advanced Chemistry reference program Development (ACD / Labs) Summer 11.02, (© 1994-2013)). Examples of volatile fragrance materials are shown in Table 2 below
















































[0084] It is understood by one skilled in the art that other volatile fragrance materials, not listed in Table 2, are also within the scope of the present invention, as long as they have a vapor pressure> 0.1 Pa (0.001 Torr) at 25 ° C. Modulators and Commodulators
[0085] In one aspect, the compositions of the present invention comprise at least one odorless modulator formed from an alkoxylated glycoside, preferably selected in the non-limiting example of the group consisting of polyol glycoside, ethyl polyol glycoside and polyol propyl glycoside . The modulator is a compound of the formula (I):
(I) where: R1 is hydrogen, alkyl, alkenyl or alkynyl; R2 is selected from hydrogen, alkyl, alkenyl or alkynyl, - [R6R7 (R8) O] wR9, where w is 1 to 10, preferably 2 to 9; R3 is selected from hydrogen, alkyl, alkenyl or alkynyl, - [R6R7 (R8) O] wR9, where y is 1 to 10, preferably 2 to 9; R4 is selected from hydrogen, alkyl, alkenyl or alkynyl, - [R6R7 (R8) O] wR9, where x is 1 to 10, preferably 2 to 9; R5 is selected from hydrogen, alkyl, 6 9 6 67 8 alkenyl or alkynyl, -ROR, -RO [RR (R) O] zR, where z is 1 to 10, preferably 2 to 9; each R6 and R7 are independently selected from alkylene, alkenylene or alkynylene; and each R8 and R9 are independently selected from hydrogen or alkyl.
[0086] In an embodiment of formula (I), in which the sum of w, y, x and z is equal to 4 to 40, preferably 8 to 36, more preferably 10 to 32, more preferably 10 to 28 or combinations thereof.
[0087] Preferably, the modulator is the undecyl glycoside and is available under the trade name Simulsol® SL 11 W from SEPPIC, France.
[0088] In another modality of formula (I), the modulator is a compound of formula (Ia):

[0089] In an embodiment of the formula (Ia), where w + y + x + z is equal to 4 to 40, preferably from 8 to 36, more preferably from 10 to 32, more preferably from 10 to 28 or combinations thereof. Preferably, the modulator is a PPG-10 methyl glucose ether available under the trade name Glucam ™ P-10 or ethoxylated methyl glucose ether and is available under the trade name Glucam ™ E-20, respectively from Lubrizol (USA). Most preferably, the modulator is a methyl glucose ether PPG-20 and is available under the trade name Glucam ™ P-20 from Lubrizol (USA).
[0090] In another modality, the modulator is a compound of formula (II):
where: R10 is hydrogen, alkyl, alkenyl or alkynyl; each R11 is independently selected from hydrogen, alkyl, alkenyl, alkynyl; each R12 is independently selected from hydrogen, alkyl, alkenyl, or alkynyl; each R13 is independently selected from hydrogen, alkyl, alkenyl, or alkynyl; each R14 is selected from alkylene, alkenylene or alkynylene; and R15 is hydrogen, alkyl, alkenyl or alkynyl; where t is 5 or less, preferably 1, 2 or 3.
[0091] Preferably, the modulator of formula (II) is caprylil / capryl glycoside and is available under the trade name Plantacare® 810 UP from BASF, Ludwigshafen, Germany.
[0092] The inventors have found that the alkoxylated glycoside acts as a modulator of the perceived intensity or longevity of the fragrance profile of the composition of the present invention when low levels of low volatility fragrance materials are used. For example, modulators act to prolong the duration that the fragrance profile can be perceived compared to a control composition in the absence of modulators. As another example, modulators can improve the intensity of the fragrance profile so that it remains significantly the same from the initial impression to the end compared to a control composition.
[0093] Without sticking to the theory, it is believed that modulators associated with fragrance materials delay evaporation.
[0094] In another aspect, the compositions of the present invention additionally comprise one or more odorless fragrance co-modulators. Fragrance comodulators consist of substances capable of increasing the intensity / longevity of the fragrance profile and, therefore, the composition, if compared to the control composition without the comodulators. In one embodiment, odorless fragrance comodulators are selected from the group consisting of: (i) Isocetyl alcohol (CERAPHYL® ICA); (ii) PPG-3 myristyl ether (preferably Tegosoft ™ APM and / or Varonic® APM); (iii) Neopentyl glycol diethylhexanoate (preferably Schercemol ™ NGDO); and (iv) mixing them, preferably, with isocetyl alcohol (CERAPHYL® ICA).
[0095] PPG-3 myristyl ether is marketed by several suppliers including: (i) Evonik-Goldschmidt under the trade name Tegosoft ™ APM; (ii) Degussa under the trade name Varonic® APM; (iii) International Specialty Products as a mixture of PPG-3 myristyl ether with isocetyl alcohol. (iv) Lubrizol Advanced Materials (USA) as a mixture of PPG-3 myristyl ether with neopentyl glycol diethylexanoate under the trade name Schercemol ™ NGDO ester; and (v) combinations thereof.
[0096] However, any commercial forms of PPG-3 myristyl ether and mixtures thereof are suitable for use as commoditizers in the compositions of the present invention.
[0097] The composition comprises the odorless fragrance commodifiers present in an amount of about 0.05% by weight to about 10% by weight, preferably from about 0.5% by weight to about 6% by weight , or combinations thereof, in relation to the total weight of the composition. Alternatively, odorless fragrance comodulators are present in an amount of about 0.05% by weight or 0.5% by weight to about 6% by weight or 10% by weight, based on the total weight of the composition. Preferably, the odorless fragrance comodulator exists as a mixture of PPG-3 myristyl ether together with CERAPHYL® ICA and Schercemol ™ NGDO ester, where PPG-3 myristyl ether is 50% by weight and the other two components of the same they are present in equal% by weight in the mixture, where% by weight is the total weight of all commodities in the composition. In particular, mixtures of PPG-3 myristyl ether with CERAPHYL® ICA, in a weight ratio of 1: 1 (PCT patent publication No. WO2013 / 064412 (Firmenich)) are preferred.
[0098] In another embodiment, the commoditizers exist as a mixture of neopentyl glycol diethylhexanoate together with CERAPHYL® ICA, where neopentyl glycol diethylhexanoate is 50% by weight and CERAPHYL® ICA is 50% by weight in the compositions are useful. Similarly, compositions of the present invention that contain at least 50% by weight of Schercemol ™ NGDO ester together with Tegosoft ™ APM have also proven to be useful for prolonging the perception of the fragrance profile from the substrate on which it was applied, in comparison with control compositions (PCT patent publication No. WO2013 / 060691 (Firmenich)).
[0099] It is understood that the addition of the commoditizers aims to further improve the intensity and / or longevity of the fragrance profile of the above composition, the improvement already provided by the modulators. Preferably, at least 50% by weight of the odorless fragrance modulator is methyl glucose ether PPG-20, with the remainder to 100% by weight possibly being one or more modulators or comodulators.
[0100] In yet another aspect, the compositions of the present invention comprise one or more odorless fragrance comodulators selected from the group consisting of: (v) Isocetyl alcohol (CERAPHYL® ICA); (vi) PPG-3 myristyl ether (preferably Tegosoft ™ APM and / or Varonic® APM); (vii) Neopentyl glycol diethylhexanoate (preferably Schercemol ™ NGDO); and (viii) mixing them, preferably, with isocetyl alcohol (CERAPHYL® ICA).
[0101] And being essentially free of odorless modulators formed from an alkoxylated glycoside selected from the group consisting of methyl glycol polyol, ethyl glycol polyol and propyl glycol polyol. As used here, the term "essentially free from" means that the composition is free of that ingredient or no ingredient is intended to be added to the composition.
[0102] In one embodiment, a composition comprises: (i) a fragrance component present in an amount of about 0.04% by weight to about 30% by weight, preferably 1% by weight to about 30% by weight, preferably less than about 25% by weight, preferably less than about 20% by weight, preferably less than about 15% by weight, preferably less than about 10% by weight or preferably less than 8% by weight, based on the total weight of the composition. and where: (a) the fragrance component comprises at least one low volatility fragrance material having a vapor pressure <0.1 Pa (0.001 Torr) at 25 ° C; and (b) the low volatility fragrance material is present in an amount of about 0.1% by weight to about 30% by weight, preferably less than about 28% by weight, preferably less than about 25% by weight, preferably less than about 22% by weight, preferably less than about 20% by weight, preferably less than about 18% by weight or preferably less than about 15% by weight relation to the total weight of the fragrance component; (ii) one or more odorless fragrance comodulators selected from the group consisting of: (a) Isocetyl alcohol (CERAPHYL® ICA); (b) PPG-3 myristyl ether (preferably Tegosoft ™ APM and / or Varonic® APM); (c) Neopentyl glycol diethylhexanoate (preferably Schercemol ™ NGDO); and (d) mixing them, preferably, with isocetyl alcohol (CERAPHYL® ICA); wherein the commodities are present in an amount of about 0.05 wt% or 0.5 wt% to about 6 wt% or 10 wt%, relative to the total weight of the composition. Testing methods
[0103] The tests described below need to be used in order for the invention described and claimed in this document to be fully understood. Test method 1: Determine the vapor pressure
[0104] In order to determine the vapor pressure for fragrance materials, visit the website: https://scifinder.cas.org/scifinder/view/scifinder/scifinder Explore.jsf and follow these steps to purchase the Steam pressure. 1. Enter the CAS registration number for the specific fragrance material. 2. Select the vapor pressure from the search results. 3. Record the vapor pressure (given in Torr at 25 ° C).
[0105] SciFinder uses Advanced Chemistry Development (ACD / Labs), Software Version 11.02. (© 19942013). If the CAS number for the specific fragrance material is unknown or does not exist, the ACD / Labs reference program can be used to directly determine the vapor pressure. Test method 2: Olfactory tests
[0106] In order to show the effect of modulators / commodities and low volatility fragrance materials on the perception of the fragrance profile in a composition of the present invention, test compositions are made, as described in the Example section, and given to examiners assess.
[0107] In the test facilities, 50 μl samples of the composition or controls are applied to the glass slides and placed on a hot plate at 32 ° to represent the skin temperature for several durations. Examiners are asked to assess the perceived fragrance profile (intensity and / or character) for each pair of samples, that is, the test composition of the present invention versus the corresponding control, at time 0 and later time points (1 , 2,3,4 and 6 hours after application) as the fragrance profile evolves. Evaluations were recorded. Examiners were selected from individuals who are trained to evaluate fragrances according to the scales below or who have experience of fragrance evaluation in the industry. (a) Fragrance intensity:
[0108] Examiners are asked to give a score on a scale of 1 to 5 for perceived fragrance intensity according to the odor intensity scale shown in Table 3 below. Table 3 - Odor intensity scale
(b) Character of the fragrance:
[0109] Examiners are asked to evaluate the character of the fragrance in one of two ways: i) a score on a scale of 0 to 3 for the dominance of specific characters that are relevant to the specific fragrance, for example, floral, pink, muguet, fruity, apple, berry, citrus, woody, musk, just to name a few, according to the odor rating scale shown in Table 4i below. ii) a score on a scale of 1 to 5 for changes in the perceived fragrance character changes for the test compositions versus the controls according to the odor rating scale shown in Table 4ii below. Table 4i - Odor classification scale for character dominance
Table 4ii - Odor classification scale for character difference


[0110] The examiner's results are weighted and then analyzed using Analysis of Variance methods. The model treats the individual as a random effect and analyzes the impact of the product, time and the interaction between the product and time. From the analysis of the minimum square, the averages for the product and time interaction are obtained. These averages (as well as their confidence intervals) are then plotted to allow comparison between products at each point in time. It should be noted that the confidence levels plotted are intended as a guide, and not as a statistical comparison, since they do not take into account that multiple tests were performed. Like graphical evaluations, statistical comparisons between the two products, at each point in time, are performed with a Sidak correction for multiple comparisons. The p-values for the differences in the products were obtained with p-values <0.05 indicating the statistical difference between the two products at 5% significance (or 95% confidence). Examples
[0111] The following examples are provided for purposes of illustration and should not be considered as limitations of the present invention, since many variations of the invention are possible without deviating from its character or scope. Examples 1 to 6 - Fragrances:
[0112] Examples 1a to 5 are non-limiting examples of fragrance material formulations intended to form the fragrance component of the compositions of the present invention. Exemplary formulations of fragrance materials range from "simple chords"(<10 fragrance materials) to "complex fragrances"(> 3 fragrance materials). Typically, full-bodied fragrance compositions comprise no less than about 30 fragrance materials. Examples 1b to 6 are examples of a fragrance material formulation intended to form the fragrance component that is outside the scope of the present invention. The following fragrance formulations are made by mixing the ingredients listed in the listed proportions (% by weight), with% by weight being relative to the total weight of the fragrance component. Table 5a - Example 1a - Soft floral chord (Fragrance I - 8.00% by weight of low volatility fragrance materials)










Examples 7 - Compositions comprising fragrance modulators
[0113] Compositions A, C, E, G and L are examples of fine fragrance compositions according to the present invention, made with fragrances I to V, respectively. They are prepared by mixing the components described in Table 11a, in the proportions indicated. In parallel, control compositions B, D, F, H and M are prepared by replacing the odorless fragrance modulator, Glucam ™ P-20, with the same amount of demineralized water. Additionally, compositions I and N are examples of a fine fragrance composition comprising excessive levels of volatile fragrance materials and compositions J and O are their corresponding controls, minus the odorless fragrance modulator, Glucam ™ P-20. Composition K is an example of a fine fragrance composition of the present invention with the modulator and commoditizer.


[0114] Compositions AA, BB, CC, DD, EE, FF, HH, II and JJ are examples of fine fragrance compositions according to the present invention, made with Fragrances I, II and V, fragrance modulators odorless: Glucam ™ P-10, Glucam ™ E-10 and Glucam ™ E-20, respectively. They are prepared by mixing the components described in Table 11b, in the proportions indicated. In parallel, the GG and KK compositions are prepared by incorporating an odorless fragrance modulator and a commoditizer (Glucam ™ P-10 and CERAPHYL ICA isocetyl alcohol) or two odorless fragrance modulators (Glucam ™ P-10, Glucam ™ P-20), respectively.

[0115] Bed compositions are examples of compositions according to the present invention, made with unique perfume raw materials and the odorless modulators Simulsol SL 11W ™ and Plantacare® 810 U, respectively. They are prepared by mixing the components described in Table 11c, in the proportions indicated. In parallel, aec control compositions are prepared without an odorless modulator as a control.

[0116] Compositions P and Q are examples of body spray compositions according to the present invention. They are prepared by mixing the components described in Table 12, in the proportions indicated.

[0117] Composition R is an example of a body lotion composition according to the present invention. It is prepared by mixing the components described in Table 13, in the proportions indicated.
Example 8 - Odor test
[0118] The compositions disclosed in Table 11a are applied to the glass slides according to the protocol described in the Method Section and a panel of 9 expert examiners evaluated the perceived fragrance profile at the initial time 0, then at various points in time, typically 1 hour, 2 hours, 3 hours, 4 hours and 6 hours after application. (a) Compositions A versus B:
[0119] Examiners are asked to score the compositions for fragrance intensity on a scale of 1 to 5, where 1 represents a detected low fragrance intensity and 5 represents a very strong detected fragrance intensity. The results of the panel test are then averaged. Figure 1 shows the effects of the fragrance modulator and the reduced levels of low volatility fragrance materials for compositions A and B on the fragrance intensity. The fragrance intensity is maintained for up to 6 hours in the presence of the modulator while it drops in the absence of the modulator. The modulator acts to maintain the continued evaporation of perfume materials over time. The effect of the improved fragrance potency of the present invention is noticeable in 3 hours and 6 hours with the indication of a statistical difference in 6 hours after application on the slides as indicated graphically by the confidence intervals. Statistical analyzes using Sidak's corrections for multiple comparisons confirm the statistically significant difference between the 2 products at 6 hours at 5% of the significance level (p = 0.0008, ie, p <0.05).
[0120] Examiners are also asked to score the composition regarding the character's dominance on a scale from 0 to 3, with 0 representing undetectable and 3 representing being the dominant character. The results of the panel test are then averaged. Figure 2 shows the effect of the fragrance modulator and the reduced levels of low volatility fragrance materials for compositions A and B on the character dominance of the muguet. The character of the muguet is reduced by the modulator at the initial time point, but is then released over the rest of the time for up to at least 6 hours. The character effect of the fragrance improved over time of the compositions of the present invention is noticeable in 3 hours and 6 hours with the indication of a statistical difference in 6 hours after application on the slides as indicated by the confidence intervals. Statistical analyzes using Sidak's corrections for multiple comparisons confirm the statistically significant difference between the 2 products at 0 hours and 6 hours at 5% of the level of significance (p = 0.0261, respectively, that is, p <0.05 ). (b) Compositions C versus D:
[0121] Examiners are asked to score the compositions for fragrance intensity on a scale of 1 to 5, where 1 represents a detected low fragrance intensity and 5 represents a very strong detected fragrance intensity. The results of the panel test are then averaged. Figure 3 shows the effects of the fragrance modulator and the reduced levels of low volatility fragrance materials for compositions C and D on the fragrance intensity. The fragrance intensity is maintained for up to 6 hours in the presence of the modulator while it drops in the absence of the modulator. The modulator acts to maintain the continued evaporation of perfume materials over time. The effect of the improved fragrance potency of the present invention is noticeable in 2 hours and 4 hours with the indication of a statistical difference in 6 hours after application on the slides as indicated graphically by the confidence intervals. Statistical analyzes using Sidak's corrections for multiple comparisons confirm the statistically significant difference between the 2 products at 4 hours at 5% of the significance level (p = 0.035, that is, p <0.05) and at 6 hours at 5 % of the level of significance (p = 0.0001, that is, p <0.05).
[0122] Examiners are asked to score compositions on a scale of 1 to 5, with 1 representing the character of the perfume remaining unchanged and 5 representing a total change in the character of the perfume. The panel test results were averaged and plotted with confidence intervals. Figure 4 shows the effects of the fragrance modulator and the reduced levels of low volatility fragrance materials for compositions C and D. The presence of the modulator results in noticeable changes in the character of the perfume. Statistical analyzes using Sidak's corrections for multiple comparisons confirm the statistically significant difference between the 2 products at 1 hour (p = 0.002, that is, p <0.05), 4 hours (p = 0.0003, that is, p <0.05) and 6 hours (p = 0.001, that is, p <0.05) at 5% of the level of significance.
[0123] Similar effects are observed for compositions E to H and L to M (data not shown). (c) Compositions N and O
[0124] Examiners are asked to score compositions for fragrance intensity on a scale of 1 to 5, where 1 represents a detected low fragrance intensity and 5 represents a very strong detected fragrance intensity. The results of the panel test are then averaged. Figure 5 shows the effect of the fragrance modulator and the excessive levels of low volatility fragrance materials for compositions N and O on the fragrance intensity. The fragrance intensity is not affected by the addition of the modulator. There are no statistical differences between the 2 products.
[0125] Examiners are also asked to score the composition regarding the character's dominance on a scale from 0 to 3, with 0 representing undetectable and 3 representing being the dominant character. The results of the panel test are then averaged. Figure 6 shows the effect of the fragrance modulator and the reduced levels of low volatility fragrance materials for compositions N and O on the character dominance of the muguet. The character of the muguet is perceived initially, but then it falls quickly over time. After 1 hour it is only slightly perceived and after 6 hours it is not present in either of the two compositions. The addition of the modulator does not result in the prolonged character release of the muguet as seen in compositions A and B. There are no significant differences between the 2 products. (d) Compositions I and J
[0126] Examiners are asked to score the compositions for fragrance intensity on a scale of 1 to 5, where 1 represents a detected low fragrance intensity and 5 represents a very strong detected fragrance intensity. The results of the panel test are then averaged. Figure 7 shows the effect of the fragrance modulator in the presence of excessive levels of low volatility fragrance materials for compositions I and J. The effects of the modulator are nullified in more traditional fragrance compositions where excessive amounts of low fragrance materials volatility are present. The fragrance appears to be suppressed with a loss of potency. This is noticeable at all points in time and appears significant as indicated graphically by the confidence intervals. Statistical analyzes using Sidak's corrections for multiple comparisons confirm the statistically significant difference between the 2 products at time 0 (p = 0.0229, that is, p <0.05), at 1 hour (p = 0.0013, that is, p <0.05), at 3 hours (p = 0.0013, that is, p <0.05) and at 6 hours (p = 0.0003, that is, p <0.05) at 5% of the level of significance.
[0127] The compositions disclosed in Table 11c are applied to the glass slides according to the protocol described in the Method Section and a panel of 8 expert examiners evaluated the perceived fragrance profile at initial time 0, then at various points in time, typically 1 hour, 3 hours, 5 hours and 6 hours after application. (e) Compositions a versus b:
[0128] Examiners are asked to score the compositions for fragrance intensity on a scale of 1 to 5, where 1 represents a detected low fragrance intensity and 5 represents a very strong detected fragrance intensity. The results of the panel test are then averaged. Figure 8 shows the effect of the Simulsol SL11W ™ odorless fragrance modulator in phenethyl alcohol. The addition of the odorless fragrance modulator maintains the intensity of the perfume raw material from 1 hour to 5 hours while the control compositions, in the absence of the odorless fragrance modulator, drop in intensity over the 5 hours. The odorless fragrance modulator acts to maintain continued evaporation over time of the perfume material. Statistical analyzes using Sidak's corrections for multiple comparisons confirm the statistically significant difference at 1 hour at 90% of the level of significance (p = 0.0933, ie, p <0.10). (f) Compositions c versus d:
[0129] Examiners are asked to score the compositions for fragrance intensity on a scale of 1 to 5, where 1 represents a detected low fragrance intensity and 5 represents a very strong detected fragrance intensity. The mean of the test results of the

权利要求:
Claims (14)
[0001]
1. Composition CHARACTERIZED for comprising: (i) a fragrance component present in an amount of 0.04% by weight to 30% by weight in relation to the total weight of the composition, and in which: (a) the fragrance component comprises at least one low volatility fragrance material having a vapor pressure less than 0.13 Pa (0.001 Torr) at 25 ° C; and (b) the low volatility fragrance material is present in an amount of 0.1% by weight to 30% by weight, relative to the total weight of the fragrance component; and (c) the fragrance component additionally comprising one or more volatile fragrance materials, having a vapor pressure greater than or equal to 0.13 Pa (0.001 Torr) at 25 ° C and present in an amount of 70% in 99.9% weight in relation to the total weight of the fragrance component; and (ii) at least one odorless fragrance modulator formed from an alkoxylated glycoside selected from the group consisting of: methyl glycoside polyol, ethyl glycoside polyol, propyl glycoside polyol, Methyl Glucose Ether PPG-10, Methyl Glucose Ether PPG-20, Methyl Glucose Etoxylated Ether, Caprylyl / Capryl Glycoside, Undecyl Glycoside or combinations thereof, in an amount of 0.1% by weight to 20% by weight relative to the total weight of the composition.
[0002]
2. Composition according to claim 1, CHARACTERIZED by the fact that the low volatility fragrance material is selected from the group consisting of: cyclopentaneacetic acid, 3-oxo-2- (2Z) -2-penten-1-il-, methyl ester, (1R, 2R) -; 2-Buten-1-ol, 2-methyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -; Ethanone, 1- (2-naphthalenyl) -; 3-Decanone, 1-hydroxy; Cyclopropanomethanol, 1-methyl-2 - [(1,2,2-trimethylbicyclo [3.1.0] hex-3-yl) methyl] -; Benzaldehyde, 3-ethoxy-4-hydroxy-; 2H-1,5-Benzodioxepin-3 (4H) -one, 7-methyl-; 2-Butanol, 1 - [[2- (1,1-dimethylethyl) cyclohexyl] oxy] -; Spiro [5.5] undec-8-en-1-one, 2,2,7,9-tetramethyl-; Cyclopentaneacetic acid, 3-oxo-2-pentyl-, methyl ester, (1R, 2R) - rel-; Cyclopentaneacetic acid, 3-oxo-2-pentyl-, methyl ester; Octanal, 2- (phenylmethylene) -; Cyclopentanecarboxylic acid, 2-hexyl-3-oxo-, methyl ester; 3- Cyclopentene-1-butanol, α, β, 2,2,3-pentamethyl-; Cyclopentanone, 2- (3,7-dimethyl-2,6-octadien-1-yl) -; 1,6,10- Dodecatrien-3-ol, 3,7,11-trimethyl-; 2-Pentenonitrile, 3-methyl-5-phenyl-, (2Z) -; Benzenepropanonitrile, 4-ethyl-α, α-dimethyl-; 1H-3a, 7-Metanoazulen-6-ol, octahydro-3,6,8,8-tetramethyl-, (3R, 3aS, 6R, 7R, 8aS) -; Ethanone, 1- (1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthalenyl) -; Propanoic acid, 2-methyl-, 4-formyl-2-methoxyphenyl ester; 1,6-Heptadien-3-one, 1- (2,6,6-trimethyl-2-cyclohexen-1-yl) -; benzoic acid, 2-hydroxy-, hexyl ester; benzoic acid, phenyl ester; Cyclohexanepropanol, 2,2,6-trimethyl-α-propyl-, (1R, 6S) -; Cyclohexanepropanol, 2,2,6-trimethyl-α-propyl-; benzoic acid, 2-hydroxy-, 3-methyl-2-buten-1-yl ester; 2H-1,5-Benzodioxepin-3 (4H) -one, 7- (1-methylethyl) -; Butanal, 4- (octahydro-4,7-methane-5H-inden-5-ylidene) -; Cyclopenta [g] -2-benzopyran, 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethyl-; Cyclopentanone, 2- [2- (4-methyl-3-cyclohexen-1-yl) propyl] -; 2 (3H) -Naftalenone, 4,4a, 5,6,7,8-hexahydro-4,4a-dimethyl-6- (1-methylethyl) -, (4R, 4aS, 6R) -; 2-Propenoic acid, 3-phenyl-, pentyl ester; 4H-Piran-4-one, 3-hydroxy-2-methyl-; 1- Propanol, 2-methyl-3 - [(1,7,7-trimethylbicyclo [2.2.1] hept-2-yl) oxyl] -; 1-Naphthalenol, 1,2,3,4,4a, 5,8,8a-octahidro- 2,2,6,8-tetramethyl-; 2-Butenoic acid, 2-methyl-, ester (2E) -3,7-dimethyl-2,6-octadien-1-yl, (2E) -; 1,3-Dioxane, 2- (2,4-dimethyl-3-cyclohexen-1-yl) -5-methyl-5- (1-methylpropyl) -; Nonadecane; 4-Penten-2-ol, 3-methyl-5- (2,2,3-trimethyl-3-cyclopenten-1-yl) -; Propanoic acid, 2-methyl-, 2-methyl-4-oxo-4H-pyran-3-yl ester; 2-Buten-1-ol, 2-ethyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -; 1,6-Methanonaftalen-1 (2H) -ol, octahydro-4,8a, 9,9-tetramethyl-, (1R, 4S, 4aS, 6R, 8aS) -; 2H-1,5-Benzodioxepin-3 (4H) -one, 7- (1,1-dimethylethyl) -; benzoic acid, phenylmethyl ester; 8-Ciclohexadecen-1-one; Benzoic acid, 2-hydroxy-, (3Z) -3-hexen-1-yl ester; 4H-Piran-4-one, 2-ethyl-3-hydroxy-; CyclopentaDecanone, 3-methyl-; Benzoic acid, 2-hydroxy-, phenylmethyl ester; 6,8-Nonadien-3-one, 2,4,4,7-tetramethyl-, oxime; Benzoic acid, 2-hydroxy-, cyclohexyl ester; Benzene, [2- (dimethoxymethyl) -1-hepten-1-yl] -; 3-Cyclopentene-1-butanol, β, 2,2,3-tetramethyl-δ-methylene-; 4-Penten-1-one, 1-spiro [4.5] dec-7-en-7-yl-; Acetic acid, 2- (1-oxopropoxy) -, 1- (3,3-dimethylcyclohexyl) ethyl ester; 2-Penten-1-ol, 5 - [(1R, 3R, 6S) - 2,3-dimethyltricyclo [2.2.1.02,6] hept-3-yl] -2-methyl-, (2Z) -; 4-Penten-2-ol, 3,3-dimethyl-5- (2,2,3-trimethyl-3-cyclopenten-1-yl) -; 5,8-Methane-2H-1-benzopyran-2-one, 6-ethylideneoctahidro-; 4-Ciclopentadecen-1-one, (4Z) -; Ethanone, 1 - [(3R, 3aR, 7R, 8aS) -2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a, 7-methanazulen-5-yl ] -; 1,3-Dioxolane, 2,4-dimethyl-2- (5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl) -; Oxacyclohexadecan-2-one; 1-Propanol, 2- [1- (3,3-dimethylcyclohexyl) ethoxy] -2-methyl-, 1-propanoate; 5- Ciclopentadecen-1-one, 3-methyl-; 2-Penten-1-ol, 2-methyl-5- [(1S, 2R, 4R) -2-methyl-3-methylenebicyclo [2.2.1] hept-2-yl] -, (2Z) -; 2H-1,5-Benzodioxepin-3 (4H) -one, 7- (3-methylbutyl) -; Ethanone, 1- (2,6,10-trimethyl-2,5,9-cyclododecatrien-1-yl) -; 1H-3a, 6-Methanazulene-3 - methanol, octahydro-7,7-dimethyl-8-methylene-, (3S, 3aR, 6R, 8aS) -; Benzenoacetonitrile, α-cyclohexylidene-; Benzoic acid, 2 - [(2-methylpentylidene) amino] -, methyl ester; Benzoic acid, 2-phenylethyl ester; 5-Ciclohexadecen-1-one; Cyclohexanol, 4- (1,7,7-trimethylbicyclo [2.2.1] hept-2-yl) -; 3-Cyclohexene-1-carboxaldehyde, 4- (4-hydroxy-4-methylpentyl) -; Ethanone, 1- (5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthalenyl) -; Ethanone, 1- (5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-; 2- cyclopentadecen-1-one, 3-methyl-; oxacycloheptadecan-2-one ; Benzenoacetic acid, 4-methylphenyl ester; Benzenoacetic acid, 2-phenylethyl ester; Cyclododecanethanol, β-methyl-; 2-Propenoic acid, 3-phenyl-, phenylmethyl ester; Benzoic acid, 2,4-dihydroxy-3,6- dimethyl-, methyl ester; Naphtho [2,1-b] furan-6 (7H) -one, 8,9-dihydro-1,5,8-trimethyl-, (8R) -; Benzenoacetic acid, (4-methoxyphenyl ) methyl ester; Benzene, 2-methoxy-1- (phenylmethoxy) -4- (1-propen-1-yl) -; Benzenoacetic acid, (2E) -3,7-dimethyl-2,6-octadien-1- il ester; Oxacyclohexadec-12-en-2-one, (12E) -; Benzoic acid, 2-hydroxy-, 2-phenylethyl ester; 2-Propenoic acid, 3-phenyl-, 1-ethylenyl-1,5-dimethyl -4-hexen-1-yl ester; Oxacycloheptadec-10-en-2-one; Oxacycloheptadec-8-en-2-one, (8Z) -; 1,7-Dioxacycloheptadecan-8-one; 7-Octen-2 -ol, 8- (1H-indol-1-yl) -2,6-dimethyl-; 1,4-Dioxacyclohexadecane-5,16-dione; 1,4- Dioxacycloheptadecane-5,17-dione; Phenol, 4- [3- (benzoyloxy) - 1-propen-1-yl] -2-methoxy -; Benzoic acid, 2 - [(1-hydroxy-3-phenylbutyl) amino] -, methyl ester; and combinations thereof.
[0003]
3. Composition according to claim 1, CHARACTERIZED in that the fragile volatile material is selected from the group consisting of formic acid, methyl ester; Methane, 1,1 '-thiobis-; Acetic acid, ethyl ester; propanoic acid, ethyl ester; acetic acid, 2-methylpropyl ester; butanoic acid, ethyl ester; 1-Butanol; butanoic acid, 2-methyl-, ethyl ester; 1-butanol, 3-methyl-, 1-acetate; butanoic acid, 2-methyl-, 1-methylethyl ester; 2- heptanone; 2-hexenal, (2E) -; 1-butanol, 3-methyl-; 2-Buten-1-ol, 3-methyl-, 1-acetate; 1,3-dioxolane-2-methanamine, N-methyl-; Bicycle [3.1.1] hept-2-ene, 2,6,6-trimethyl-, (1R, 5R) -; Bicycle [2.2.1] heptane, 2,2-dimethyl-3-methylene-; 2- Butanetiol, 4-methoxy-2-methyl-; Pentanoic acid, 2-methyl-, ethyl ester; Bicycle [3.1.0] hexane, 4-methylene-1- (1-methylethyl) -; Bicycle [3.1.1] heptane, 6,6-dimethyl-2-methylene-; 1-Butanol, 3-methyl-, 1-propanoate; 1,6-Octadiene, 7-methyl-3-methylene-; Octanal; 2H-Pyran, 2-ethenyltetrahydro-2,6,6-trimethyl-; 2-Octanone; Hexanoic acid, ethyl ester; 2-Oxabicyclo [2.2.2] octane, 1,3,3-trimethyl-; Benzene, 1-methyl-4- (1-methylethyl) -; Benzene, 1-methoxy-4-methyl-; 1,3,6- Octatriene, 3,7-dimethyl-; Cyclohexene, 1-methyl-4- (1-methylethyl) -; Cyclohexene, 1-methyl-4- (1-methylethyl) -, (4R) -; 3-Octanone; Undecanal, 2-methyl-; Acetic acid, hexyl ester; 5-Hepten-2-one, 6-methyl-; 2-Hepten-4-one, 5-methyl-; 3-Hexen-1-ol, 1-acetate, (3Z) -; 3-Hexen-1-ol, 1-acetate; Propanoic acid, 2-hydroxy-, ethyl ester; Butanoic acid, 2-methylbutyl ester; Butanoic acid, 3-methylbutyl ester; 1,4-Cyclohexadiene, 1-methyl-4- (1-methylethyl) -; Thiazole, 2- (2-methylpropyl) -; 3-Hexen-1-ol, (3Z) -; Benzaldehyde; Butanoic acid, 3-oxo-, ethyl ester; 2- Hexen-1-ol, (2E) -; 2-Hexen-1-ol, (2Z) -; Cyclohexane, 3-ethoxy-1,1,5-trimethyl-, cis- (9CI); 2-Pentanone, 4-mercapto-4-methyl-; 2,4,6-Octatriene, 2,6-dimethyl-, (4E, 6E) -; Oxirane, 2,2-dimethyl-3- (3-methyl-2,4-pentadien-1-yl) -; 4,7- Octadienoic acid, methyl ester, (4E) -; Carbonic acid, (3Z) -3-hexen-1-yl methyl ester; Hexanoic acid, 2-propen-1-yl ester; 5-Heptenal, 2,6-dimethyl-; Heptanoic acid, ethyl ester; 3-Cyclohexene-1-carboxaldehyde, 2,4-dimethyl-; Benzene, (2,2-dimethoxyethyl) -; 2H-Pyran, tetrahydro-4-methyl-2- (2-methyl-1-propen-1-yl) -; 3-Nonanone; Benzonitrile; 3-Octanol; 1-Hexanol, 3,5,5-trimethyl-, 1-acetate; 4- Heptanol, 2,6-dimethyl-, 4-acetate; Hexanoic acid, 2-methylpropyl ester; Propanoic acid, 2-methyl-, hexyl ester; Cyclohexanecarboxylic acid, 1,4-dimethyl-, methyl ester, trans-; Benzeneacetaldehyde; Butanoic acid, 3-hydroxy-, ethyl ester; Propanedioic acid, 1,3-diethyl ester; Benzoic acid, methyl ester; 1,3,5-Undecatriene; 4-Decennial, (4E) -; 1,3-Dioxane, 2-butyl-4,4,6-trimethyl-; 2-Heptanol, 2,6-dimethyl-; Ethanone, 1-phenyl-; Benzenoacetaldehyde, α-methyl-; Propanoic acid, 2-methyl-, 1,3-dimethyl-3-buten-1-yl ester; 2,6-Nonadienal, (2E, 6Z) -; Pirazine, 2-methoxy-3- (2-methylpropyl) -; Formic acid, phenylmethyl ester; Benzene, 1-methoxy-4-propyl-; Cyclohexanone, 5-methyl-2- (1-methylethyl) -, (2R, 5R) -rel-; Cyclohexanone, 5-methyl-2- (1-methylethyl) -, (2R, 5S) -rel-; 2-Nonenal; Cyclohexanone, 2-ethyl-4,4-dimethyl-; Benzene, 1,4-dimethoxy-; Benzene, 1- (ethoxymethyl) -2-methoxy-; Bicycle [2.2.1] heptan-2-one, 1,7,7-trimethyl-; 2-Hexene, 6,6-dimethoxy-2,5,5-trimethyl-; Decanal; Benzenepropanal, β-methyl-; Benzenomethanol, α-methyl-, 1-acetate; Acetic acid, nonyl ester; Ethanone, 1- (4-methylphenyl) -; 2H-Pyran, 6-butyl-3,6-dihydro-2,4-dimethyl-; Propanoic acid, 2-methyl-, (3Z) -3-hexen-1-yl ester; Benzoic acid, ethyl ester; 3- Octanol, 3,7-dimethyl-, 3-acetate; 1-Hexanol, 5-methyl-2- (1-methylethyl) -, 1-acetate; Cyclohexanol, 3,3,5-trimethyl-, (1R, 5R) -rel-; 2-Hexenal, 5-methyl-2- (1-methylethyl) -; 7-Octen-2-ol, 2,6-dimethyl-; Acetic acid, phenylmethyl ester; Cyclohexanone, 2- (1-methylpropyl) -; 3-Octen-1-ol, (3Z) -; Heptanoic acid, 2-propen-1-yl ester; Benzenomethanol; Butanoic acid, 2-methyl-, hexyl ester; 2 (3H) -Furanone, 5-ethylhydro-; Cyclohexaneethanol, 1-acetate; 2-Nonenoic acid, methyl ester; Butanoic acid, (3Z) -3-hexen-1-yl ester; 2-Octinoic acid, methyl ester; 1,3-Oxatian, 2-methyl-4-propyl-, (2R, 4S) -rel-; Heptanal, 6-methoxy-2,6-dimethyl-; Bicycle [2.2.1] heptan-2-ol, 1,3,3-trimethyl-, 2-acetate; 1,6-Octadien-3-ol, 3,7-dimethyl-, 3-acetate; 2- Octanol, 2,6-dimethyl-; 1-Octanol; 3-Cyclohexene-1-methanethiol, α, α, 4-trimethyl-; Cyclohexanomethanol, α, α, 4-trimethyl-, 1-acetate; Cyclohexanol, 2- (1,1-dimethylethyl) -, 1-acetate; Cyclohexanol, 4- (1,1-dimethylethyl) -, 1-acetate; Pirazine, 2-methoxy-3- (1-methylpropyl) -; Cyclohexanol, 5-methyl-2- (1-methylethyl) -, (1R, 2S, 5R) -; 2-Undecanone; Benzenepropanol, α, α-dimethyl-; Bicycle [2.2.1] heptan-2-ol, 1,7,7-trimethyl-, 2-acetate, (1R, 2R, 4R) -rel-; 1,6-Octadien-3-ol, 3,7-dimethyl-; Benzene acetic acid, ethyl ester; Benzeneethanol, α, α-dimethyl-; Cyclopropanecarboxylic acid, (3Z) -3-hexen-1-yl ester; 3-Cyclohexene-1-methanol, 3,5-dimethyl-, 1-acetate; Undecanal; Ethanone, 1- (3-cycloocten-1-yl) -; Cyclohexanone, 4- (1,1-dimethylethyl) -; 6-Nonen-1-ol, (6Z) -; Benzene, (2-butoxyethyl) -; Bicycle [3.1.1] hept-3-en-2-one, 4,6,6-trimethyl-; Cyclohexanecarboxylic acid, 2,2,6-trimethyl-, ethyl ester, (1R, 6S) -rel-; Benzeneethanol; 2,6- Octadienal, 3,7-dimethyl-, (2Z) -; 2,6-Octadienal, 3,7-dimethyl-; Cyclohexanol, 5-methyl-2- (1-methylethyl) -, 1-acetate, (1R, 2S, 5R) -rel-; Benzoic acid, 2-hydroxy-, methyl ester; Benzene, 1-methoxy-4- (1E) -1-propen-1-yl-; 2,6- Octadiene, 1,1-dimethoxy-3,7-dimethyl-; Cyclohexanomethanol, a, 3,3-trimethyl-, 1-formate; 2-Decennial, (2E) -; 3- Cyclopentene-1-acetonitrile, 2,2,3-trimethyl-; 2-Cyclohexen-1-one, 2-methyl-5- (1-methylethyl) -, (5R) -; Cyclohexanone, 4- (1,1-dimethylpropyl) -; 6,10-Dioxaspiro [4.5] decane, 8,8-dimethyl-7- (1-methylethyl) -; 2-Cyclohexen-1-one, 3-methyl-5-propyl-; Benzonitrile, 4- (1-methylethyl) -; 2,6- Nonadienonitrile; Butanoic acid, 2-methyl-, (3Z) -3-hexen-1-yl ester; Benzene, 1- (cyclopropylmethyl) -4-methoxy-; 2- Noninoic acid, methyl ester; Acetic acid, 2-phenylethyl ester; Cyclohexanol, 2- (1,1-dimethylethyl) -; 2,6-Nonadien-1-ol; Propanoic acid, 2-methyl-, phenylmethyl ester; Bicycle [2.2.1] heptan-2-ol, 1,2,3,3-tetramethyl-, (1R, 2R, 4S) - rel-; Benzaldehyde, 4- (1-methylethyl) -; 2,5-Octadien-4-one, 5,6,7-trimethyl-, (2E) -; 3-Cyclohexen-1-ol, 4-methyl-1- (1-methylethyl) -; 3-Cyclohexene-1-methanol, 2,4,6-trimethyl-; Pentanoic acid, (3Z) -3-hexen-1-yl ester; Bicycle [2.2.1] heptan-2-ol, 1,7,7-trimethyl-, 2-propanoate, (1R, 2R, 4R) -rel-; Benzene, 1-methyl-4- (1-methylethyl) -2- (1-propen-1-yl) -; 3-Cyclohexene-1-propanal, β, 4-dimethyl-; 1- Hexanol, 5-methyl-2- (1-methylethyl) -, (2R) -; 3-Heptanone, 5-methyl-, oxime; 2 (3H) -Furanone, 5-butyldihydro-; 1-Nonanol; Acetic acid, 2- (3-methylbutoxy) -, 2-propen-1-yl ester; Bicycle [2.2.1] heptan-2-ol, 1,7,7-trimethyl-, (1S, 2R, 4S) -; Bicycle [2.2.1] heptan-2-ol, 1,7,7-trimethyl-, (1R, 2R, 4R) -rel-; Cyclohexanol, 2- (1,1-dimethylpropyl) -, 1-acetate; 3- Cyclohexene-1-methanol, α, α, 4-trimethyl-, 1-acetate; Cyclohexanomethanol, α, α, 4-trimethyl-; 10-Undecenal; 2,4- Cyclohexadiene-1-carboxylic acid, 2,6,6-trimethyl-, ethyl ester; 1-Octanol, 3,7-dimethyl-; Furan, tetrahydro-2,4-dimethyl-4-phenyl-; Benzene, [2- (3-methylbutoxyl) ethyl] -; Butanoic acid, phenylmethyl ester; Benzoic acid, 2-hydroxy-, ethyl ester; Cyclohexanol, 4- (1,1-dimethylethyl) -; 1,6-Octadien-3-ol, 3,7-dimethyl-, 3-formate; Dodecanal; 3.6- Nonadien-1-ol, (3Z, 6Z) -; 3,6-Nonadien-1-ol; Decanonitrile; Cyclohexanol, 5-methyl-2- (1-methylethyl) -, (1R, 2S, 5R) -; Propanoic acid, 2-methyl-, 4-methylphenyl ester; Propanoic acid, 2-methyl-, (1R, 2S, 4R) -1,7,7-trimethylbicyclo [2.2.1] hept-2-yl ester, rel-; Acetaldehyde, 2- (4-methylphenoxy) -; 2-butenoic acid, 2-methyl-, (3Z) -3-hexen-1-yl ester, (2E) -; Bicycle [3.1.1] hept-2-ene-2-propanal, 6,6-dimethyl-; 2- Nonanol, 6,8-dimethyl-; Cyclohexanol, 1-methyl-3- (2-methylpropyl) -; 1H-Indole; 2-Undecenal; 2H-Piran-2-one, 4,6-dimethyl-; 3-Cyclohexene-1-methanol, α, α, 4-trimethyl-; 3- Hepten-2-one, 3,4,5,6,6-pentamethyl-, (3Z) -; 2 (3H) -Furanone, 5-butyldihydro-4-methyl-; 7-Octen-2-ol, 2,6-dimethyl-, 2-acetate; 2-Propenal, 3-phenyl-; 1,6-Octadien-3-ol, 3,7-dimethyl-, 3-propanoate; 1,6-Nonadien-3-ol, 3,7-dimethyl-, 3-acetate; Cyclopentanone, 2,2,5-trimethyl-5-pentyl-; 2,6- Octadien-1-ol, 3,7-dimethyl-, 1-acetate, (2Z) -; 2,6- Octadien-1-ol, 3,7-dimethyl-, 1-acetate, (2E) -; Undecane, 1,1-dimethoxy-2-methyl-; Benzenomethanol, α-methylene-, 1-acetate; Benzaldehyde, 4-methoxy-; Cyclohexanol, 5-methyl-2- (1-methylethyl) -, 1-acetate, (1R, 2S, 5R) -; 6-Octenenitrile, 3,7-dimethyl-; 6-Octen-2-ol, 2,6-dimethyl-; Benzene, 1,1 '-oxybis-; Benzoic acid, butyl ester; 5,8-Methane-2H-1-benzoPyrane, 6-ethylideneoctahidro-; Cyclohexanepropanol, α, α-dimethyl-; Benzenepropanal, β-methyl-3- (1-methylethyl) -; Benzenomethanol, 4-methoxy-, 1-acetate; Phenol, 2-ethoxy-4-methyl-; Benzene, [2- (1-propoxyethoxy) ethyl] -; 7-Octen-1-ol, 3,7-dimethyl-; Bicycle [4.3.1] decane, 3-methoxy-7,7-dimethyl-10-methylene-; Propanoic acid, 2- (1,1-dimethylpropoxy) -, propyl ester, (2S) -; Benzoic acid, 2- (methylamino) -, methyl ester; 6-Octen-1-ol, 3,7-dimethyl-, (3S) -; 7-Octen-2-ol, 2-methyl-6-methylene-; 4,6-Octadien-3-ol, 3,7-dimethyl-; 5- Oxatriciclo [8.2.0.04.6] dodecane, 4,9,12,12-tetramethyl-; 2- Cyclohexene-1-carboxylic acid, 2-ethyl-6,6-dimethyl-, ethyl ester; 3-Buten-2-one, 4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -, (3E) -; 4,7-Methane-1H-inden-5-ol, octahydro-, 5-acetate; Benzoic acid, 2-amino-, methyl ester; spiro [1,3-dioxolane-2,8 '(5' H) - [2H-2,4a] methanonaphthalene], hexahydro-1 ', 1', 5 ', 5'-tetramethyl-, (2'S, 4'aS, 8'aS) - (9CI); spiro [1,3-dioxolane-2,8 ‘(5‘ H) - [2H-2,4a] methanonaphthalene], hexahydro-1 ‘, 1‘, 5 ‘, 5’-tetramethyl-; 3-Buten-2-one, 4- (2,6,6-trimethyl-2-cyclohexen-1-yl) -, (3E) -; Benzeneethanol, α, α-dimethyl-, 1-acetate; 4,7-Methane-1H-inden-5-ol, 3a, 4,5,6,7,7a-hexahydro-, 5-acetate; 6-Octen-1-ol, 3,7-dimethyl-, 1-acetate; 2H- Pyran, tetrahydro-2-methyl-4-methylene-6-phenyl-; Bicycle [3.3.1] nonane, 2-ethoxy-2,6,6-trimethyl-9-methylene-; 2,6-Octadien-1-ol, 3,7-dimethyl-, (2E) -; Bicycle [7.2.0] undec-4-ene, 4,11,11-trimethyl-8-methylene-, (1R, 4E, 9S) -; 1H-3a, 7-Methanazulene, octahydro-6-methoxy- 3,6,8,8-tetramethyl-, (3R, 3aS, 6S, 7R, 8aS) -; Bicycle [7.2.0] undec-4-ene, 4,11,11-trimethyl-8-methylene-, (1R, 4E, 9S) -; 1H-Inden-1-one, 2,3-dihydro-2,3,3-trimethyl-; 2-Propanol, 1,1 '-oxybis-; 2-Octanol, 7-methoxy-3,7-dimethyl-; 4,9-Decadienal, 4,8-dimethyl-; Benzoic acid; 3-Hexenoic acid, (3Z) -3-hexen-1-yl ester, (3Z) -; Bicycle [2.2.1] hept-5-ene-2-carboxylic acid, 3- (1-methylethyl) -, ethyl ester, (1R, 2S, 3S, 4S) -rel-; 2-Propen-1-ol, 3-phenyl-; Propanoic acid, 2-methyl-, 1-ethylenyl-1,5-dimethyl-4-hexen-1-yl ester; Ethanol, 2-phenoxy-, 1-propanoate; 2-Propenoic acid, 3-phenyl-, methyl ester; Benzenepropanal, 2-ethyl-α, α-dimethyl-; Propanoic acid, decyl ester; Benzene, 1,2-dimethoxy-4- (1-propen-1-yl) -; 3-Decen-5-ol, 4-methyl-; Phenol, 2-methoxy- 4- (2-propen-1-yl) -; 1-Propanone, 1- [2-methyl-5- (1-methylethyl) -2-cyclohexen-1-yl] -; 1,3-Benzodioxol-5-carboxaldehyde; 2-Dodecenal; 2-Dodecenal, (2E) -; Benzenepropanal, 4-methoxy-a-methyl-; 1,4-Cyclohexanedicarboxylic acid, 1,4-dimethyl ester; 2-Buten-1-one, 1- (2,6,6-trimethyl-3-cyclohexen-1-yl) -; 2-Butanone, 4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -; 2-Propenenitrile, 3-phenyl-, (2E) -; Propanoic acid, 2-methyl-, 2-phenylethyl ester; 2-Cyclopenten-1-one, 3-methyl-2- (2Z) -2-penten-1-yl-; Acetaldehyde, 2 - [(3,7-dimethyl-6-octen-1-yl) oxy] -; 1- Cyclohexene-1-ethanol, 4- (1-methylethyl) -, 1-formate; 2,4-Decadienic acid, ethyl ester, (2E, 4Z) -; 2-Propen-1-ol, 3-phenyl-, 1-acetate; Naphthus [2,1-b] furan, dodecahydro-3a, 6,6,9a-tetramethyl-, (3aR, 5aS, 9aS, 9bR) -; Benzenepropanal, 4- (1,1-dimethylethyl) -; Naphthus [2,1-b] furan, dodecahydro-3a, 6,6,9a-tetramethyl-; 1,4-Methanonaphthalen-5 (1H) -one, 4,4a, 6,7,8,8a-hexahydro-; Dodecanoic acid, 12-hydroxy-, Î ± -lactone (6CI, 7CI); 1.12-; Propanoic cyclohexanoacid, 2-propen-1-yl ester; 2 (3H) -Furanone, 5-hexyldhydro-5-methyl-; 2,6-Nonadienonitrile, 3,7-dimethyl-; 10-Undecenoic acid, ethyl ester; Benzenepropanal, α-methyl- 4- (1-methylethyl) -; 1-Oxaspiro [4.5] decan-2-one, 8-methyl-; 2 (3H) -Furanone, dihydro-5-pentyl-; 2 (3H) -Furanone, 5-hexyldhydro-; 2-Buten-1-one, 1- (2,6,6-trimethyl-2-cyclohexen-1-yl) -, (2E) -; 2-Buten-1-one, 1- (2,4,4-trimethyl-2-cyclohexen-1-yl) -, (2E) -; 2H-Piran-2-one, tetrahydro-6-pentyl-; Benzenepropanal, 4-ethyl-α, α-dimethyl-; 1,3- Benzodioxol, 5- (diethoxymethyl) -; 4-Penten-1-one, 1- (5,5-dimethyl-1-cyclohexen-1-yl) -; Bicycle [3.1.1] hept-2-ene-2-ethanol, 6,6-dimethyl-, 2-acetate; 2-Propenoic acid, 3-phenyl-, ethyl ester; 1,3-Dioxane, 2,4,6-trimethyl-4-phenyl-; Cyclododecane, (methoxymethoxy) -; Bicycle [3.1.1] hept-2-ene-2-propanal, α, α, 6,6-tetramethyl-; Benzenoacetonitrile, 4- (1,1-dimethylethyl) -; 2-Buten-1-one, 1- (2,6,6-trimethyl-1-cyclohexen-1-yl) -; 1,4-Methanonaftalen-6 (2H) -one, octahydro-7-methyl-; Bicycle [3.2.1] octan-8-one, 1,5-dimethyl-, oxime; Benzenopentanol, Y-methyl-; Cyclohexene, 4- (1,5-dimethyl-4-hexen-1-ylidene) -1-methyl-; Phenol, 2-methoxy-4-propyl-; Benzoic acid, 2-hydroxy-, 2-methylpropyl ester; 2H-1-Benzopyran-2-one, octahidro-; Cyclohexanone, 2- (1-mercapto-1-methylethyl) -5-methyl-; 2-Oxiranecarboxylic acid, 3-methyl-3-phenyl-, ethyl ester; 3-Cyclohexene-1-carboxaldehyde, 4- (4-methyl-3-penten-1-yl) -; Propanoic acid, 2-methyl-, 2-phenoxyethyl ester; Indeno [1,2-d] -1,3-dioxin, 4,4a, 5,9b-tetrahydro-; 2H-Piran-4-ol, tetrahydro-4-methyl-2- (2-methylpropyl) -; Cyclohexanobutanal, α, 2,6,6-tetramethyl-; 1,6-Nonadien-3-ol, 3,7-dimethyl-; 3-Buten-2-one, 4- (2,2,6-trimethyl-7-oxabicyclo [4.1.0] hept-1-yl) -; Phenol, 2-methoxy-4- (1-propen-1-yl) -; 2 (3H) -Furanone, 5-hexyldhydro-4-methyl-; 1-Penten-3-one, 1- (2,6,6-trimethyl-2-cyclohexen-1-yl) -; 2- Buten-1-one, 1- (2,6,6-trimethyl-1,3-cyclohexadien-1-yl) -; 2- Cyclopenten-1-one, 2-hydroxy-3-methyl-; Propanoic acid, 2,2-dimethyl-, 2-phenylethyl ester; Dodecanonitrile; 6-Octen-1-ol, 3,7-dimethyl-, 1-propanoate; Benzenopentanal, β-methyl-; Acetic acid, 2-phenoxy-, 2-propen-1-yl ester; Benzenepropanal, 4- (1,1-dimethylethyl) -α-methyl-; 4,7-Methane-1H-Indene-2-carboxaldehyde, octahydro-5-methoxy-; Pentitol, 1,5-anhydro-2,4-dideoxy-2-pentyl-, 3-acetate; Cyclododecane, (ethoxymethoxy) -; 3-Buten-2-one, 4- (2,5,6,6-tetramethyl-2-cyclohexen-1-yl) -; Quinoline, 6- (1-methylpropyl) -; Carbonic acid, 4-cycloocten-1-yl methyl ester; 1H-Indeno-5-propanal, 2,3-dihydro-3,3-dimethyl-; Ethanone, 1- (3-methyl-2-benzofuranyl) -; 3-Cyclohexene-1-carboxaldehyde, 1-methyl-3- (4-methyl-3-penten-1-yl) -; 6- Oxabicyclo [3.2.1] octane, 5-methyl-1- (2,2,3-trimethyl-3-cyclopenten-1-yl) -; 2H-Piran-2-one, tetrahydro-6- (3-pentent-1-yl) -; 2,4,7-Decatrienoic acid, ethyl ester; Butanoic acid, 3-methyl-, 2-phenylethyl ester; spiro [1,4-methanonaphthalene-2 (1H), 2 ‘-Oxirane], 3,4,4a, 5,8,8a-hexahydro-3’, 7-dimethyl-; Ethanol, 2 - [[((1R, 2R, 4R) -1,7,7-trimethylbicyclo [2.2.1] hept-2-yl] oxy] -, rel-; Phenol, 2-methoxy-4- (1-propen-1-yl) -, 1-acetate; 2H-Indeno [4,5-b] furan, decahydro-2,2,6,6,7,8,8-heptamethyl-; Acetic acid, 2- (cyclohexyloxy) -, 2-propen-1-yl ester; Octanal, 7-hydroxy-3,7-dimethyl-; Naphthus [2,1-b] furan, 9b-ethyldodecahydro-3a, 7,7-trimethyl-; 1,6-Heptadien-3-one, 2-cyclohexyl-; 5-Thiazoleethanol, 4-methyl-; 1-Penten-3-one, 1- (2,6,6-trimethyl-2-cyclohexen-1-yl) -; 3-Buten-2-one, 3-methyl-4- (2,6,6-trimethyl-2-cyclohexen-1-yl) -; 1,4-Cyclohexanedicarboxylic acid, 1,4-diethyl ester; 2 (3H) -Furanone, 5-heptyldihydro-; 1,3-Benzodioxol-5-propanal, α-methyl-; 4H- Inden-4-one, 1,2,3,5,6,7-hexahydro-1,1,2,3,3-pentamethyl-; Cyclohexanone, 4- (1-ethoxyethyl) -3,3,5,5-tetramethyl-; Benzenepropanonitrile, α-ethylenyl-α-methyl-; 9-Undecenal, 2,6,10-trimethyl-; pyridine, 2- (3-phenylpropyl) -; Indeno [1,2-d] -1,3-dioxin, 4,4a, 5,9b-tetrahydro-2,4-dimethyl-; Propanoic acid, 2-methyl-, 3a, 4,5,6,7,7a-hexahydro-4,7-methane-1H-inden-5-yl ester; 1-Naphthalenol, 1,2,3,4,4a, 7,8,8a-octahydro-2,4a, 5,8a-tetramethyl-, 1-format; Benzenepropanol, β, β, 3-trimethyl-; 2-Cyclohexen-1-one, 4- (2-buten-1-ylidene) -3,5,5-trimethyl-; 3-Hexen-1-ol, 1-benzoate, (3Z) -; Benzaldehyde, 4-hydroxy-3-methoxy-; 1H-3a, 7- Metanoazulen-6-ol, octahydro-3,6,8,8-tetramethyl-, 6-acetate, (3R, 3aS, 6R, 7R, 8aS) -; 4,7-Methane-1H-inden-6-ol, 3a, 4,5,6,7,7a-hexahydro-8,8-dimethyl-, 6-propanoate; 2-Oxiranecarboxylic acid, 3-phenyl-, ethyl ester; 4H-4a, 9- Metanoazulene [5,6-d] -1,3-dioxol, octahydro-2,2,5,8,8,9a- hexamethyl-, (4aR, 5R, 7aS, 9R) -; Butanoic acid, 1,1-dimethyl-2-phenylethyl ester; Cyclododeca [c] furan, 1,3,3a, 4,5,6,7,8,9,10,11,13a-dodecahydro-; Benzenobutanenitrile, a, a, y-trimethyl-; 2-Butanone, 4- (1,3-benzodioxol-5-yl) -; Benzoic acid, 4-hydroxy-3-methoxy-, methyl ester; 3-Cyclopentene-1-butanol, β, 2,2,3-tetramethyl-2-Methyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) butanol; 2- Butenal, 2-methyl-4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -; 2- Naphthalenol, decahydro-2,5,5-trimethyl-; 1,7-Octanodiol, 3,7-dimethyl-; 2H-1-Benzopyran-2-one; 1,3-Dioxolane, 2- [6-methyl-8- (1-methylethyl) bicyclo [2.2.2] oct-5-en-2-yl] -; Propanoic acid, 2,2-dimethyl-, 3a, 4,5,6,7,7a-hexahydro-4,7-methane-1H-inden-6-yl ester; Butanoic acid, (2E) -3,7-dimethyl-2,6-octadien-1-yl ester; 2-Butanone, 4- (4-hydroxyphenyl) -; 10-Undecenoic acid, butyl ester; and combinations thereof.
[0004]
4. Composition according to claim 1, CHARACTERIZED in that the volatile fragrance material is selected from the group consisting of: (i) a highly volatile fragrance material having a vapor pressure greater than 13 Pa (0.1 Torr) at 25 ° C; (ii) a medium volatility fragrance material having a vapor pressure in the range of 13 Pa (0.1 Torr) at 25 ° C to 0.13 Pa (0.001 Torr) at 25 ° C; and (iii) combinations thereof.
[0005]
Composition according to claim 1, characterized in that it additionally comprises ethanol in the amount of 50% by weight to 80% by weight, in relation to the total weight of the composition.
[0006]
6. Composition, according to claim 1, CHARACTERIZED by additionally comprising one or more odorless fragrance comodulators selected from the group consisting of: (i) Isocetyl alcohol; (ii) PPG-3 myristyl ether; (iii) Neopentyl glycol diethylexanoate; and (iv) mixing them, one or more of the odorless fragrance comodulators are present in the amount of 0.05% by weight to 10% by weight in relation to the total weight of the composition.
[0007]
7. Composition according to claim 6, CHARACTERIZED in that the odorless fragrance modulators are formed of at least 50% by weight of an odorless fragrance modulator, in relation to the total weight of the odor fragrance modulators and the commoditizers odorless fragrance.
[0008]
8. Composition according to claim 6, further comprising one or more odorless fragrance comodulators selected from the group consisting of isocetyl alcohol, myristyl ether PPG-3, neopentyl glycol diethylexanoate, and mixtures thereof, preferably with isocetyl alcohol present in the amount of 0.5% by weight to 6% by weight, in relation to the total weight of the composition.
[0009]
9. Composition, according to claim 1, CHARACTERIZED for being in the form of a perfume, eau de toilette, eau de parfum, cologne, perfumed water or a body spray.
[0010]
10. Method to accentuate the fragrance profile of a composition, preferably to improve the longevity of an aroma, preferably a floral aroma, of a composition, FEATURED by understanding to contact or mix at least one fragrance modulator without odor with minus a low volatility fragrance material of a composition as defined in claim 1.
[0011]
11. Method according to claim 12, CHARACTERIZED in that the floral aroma is selected from the group consisting of lavender notes, a pink note, a lily-of-the-valley note, a muguet note, a jasmine note, a magnolia note, a cyclamen note, a hyacinth note, a lilac note, an orange blossom note, a cherry blossom note, a cherry blossom note peony, a lotus note, a linden note, an osmantus note, a heliotrope note, a violet note, an orris root note, a tiaré note and combinations thereof.
[0012]
12. Method for producing a product for the consumer CHARACTERIZED for comprising bringing into contact with or mixing with the product an organoleptically active amount of a fragrance composition as defined in claim 1.
[0013]
13. Consumer perfumery product or article comprising a fragrance composition as defined in claim 1 CHARACTERIZED that the consumer perfumery product is selected from the group consisting of fabric care products, air care products or care products with the house.
[0014]
14. Method for modifying or improving the odor properties of a body surface CHARACTERIZED by understanding to contact or treat the body surface with a composition as defined in claim 1.

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公开号 | 公开日 | 专利标题

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BR112016013533B1|2020-12-15|COMPOSITION, METHOD TO INCREASE THE FRAGRANCE PROFILE OF A COMPOSITION, METHOD TO PRODUCE A CONSUMER PRODUCT, PRODUCT OR PERFUMER ARTICLE FOR CONSUMER AND METHOD OF MODIFYING OR IMPROVING THE ODOR PROPERTIES OF A CORPORATE SURFACE

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---

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同族专利:

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公开号 | 公开日

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US20150164764A1|2015-06-18|

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CN106061459A|2016-10-26|

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US9814661B2|2017-11-14|

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WO2015089246A1|2015-06-18|

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BR112016013533B8|2021-04-13|

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EP2961374A1|2016-01-06|

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CN106061459B|2020-06-19|

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EP2961374B1|2017-01-25|

引用文献:

---

公开号 | 申请日 | 公开日 | 申请人 | 专利标题

---

---

US4264478A|1978-10-30|1981-04-28|Amerchol Corporation|Polyol fragrance fixatives|

---

US4324703A|1979-12-26|1982-04-13|Amerchol Corporation|Polyol fragrance fixatives|

---

CH654204A5|1980-03-14|1986-02-14|Kao Corp|PERFUME COMPOSITIONS AND PROCEDURE FOR THEIR PREPARATION.|

---

US6126930A|1997-02-13|2000-10-03|The Procter & Gamble Company|Spray compositions|

---

US5928631A|1997-06-09|1999-07-27|The Procter & Gamble Company|Methods for controlling environmental odors on the body using compositions comprising uncomplexed cyclodextrins|

---

EP2579839B1|2010-06-10|2016-01-13|Firmenich SA|Perfuming compositions and uses thereof|

---

EP2771071B1|2011-10-27|2019-08-07|Firmenich SA|Perfuming compositions and uses thereof|

---

ES2762253T3|2011-11-04|2020-05-22|Firmenich & Cie|Perfume compositions and uses thereof|

---

CN109568166B|2012-12-14|2022-01-28|宝洁公司|Fragrance materials|CN109568166B|2012-12-14|2022-01-28|宝洁公司|Fragrance materials|

---

EP3307231A1|2015-06-12|2018-04-18|The Procter and Gamble Company|Fragrance compositions and uses thereof|

---

EP3103431A1|2015-06-12|2016-12-14|The Procter and Gamble Company|Fragrance compositions and uses thereof|

---

EP3103523A1|2015-06-12|2016-12-14|The Procter and Gamble Company|Absorbent article comprising fragrance composition|

---

JP2018524457A|2015-07-20|2018-08-30|高砂香料工業株式会社|Hygiene fragrance composition|

---

GB201521861D0|2015-12-11|2016-01-27|Givaudan Sa|Improvements in or relating to organic compounds|

---

US10035972B2|2015-12-11|2018-07-31|Bedoukian Research, Inc.|Fragrance and flavor compositions containing isomeric alkadienals or isomeric alkadienenitriles|

---

WO2018005839A1|2016-06-29|2018-01-04|Takasago International Corporation |Fragrance compositions and methods of use thereof|

---

WO2018002298A1|2016-06-30|2018-01-04|Firmenich Sa|Perfuming compositions|

---

JP6949061B2|2016-06-30|2021-10-13|フイルメニツヒ ソシエテ アノニムＦｉｒｍｅｎｉｃｈ Ｓａ|Fragrant composition|

---

GB201615581D0|2016-09-14|2016-10-26|Givauden Sa|Improvements in or relating to organic compounds|

---

US10952434B2|2016-12-30|2021-03-23|The United States Of America, As Represented By The Secretary Of Agriculture|Compositions and methods for attracting insects|

---

EP3746039A1|2018-02-07|2020-12-09|Coty Inc.|Fragrance compositions and uses thereof|

---

US20210393506A1|2018-11-06|2021-12-23|Noor Al-Rifai|Fragrance blends and methods for preparation thereof|

---

EP3897865A1|2019-05-17|2021-10-27|Firmenich SA|Fragrance compositions|

---

CN110812522A|2019-11-27|2020-02-21|广州联丰香料科技有限公司|Flock essence and application thereof|

---

CN112023101A|2020-09-10|2020-12-04|苏州花仙子环保科技有限公司|Air freshener composition|

法律状态:
2019-08-13| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2020-06-16| B06A| Notification to applicant to reply to the report for non-patentability or inadequacy of the application [chapter 6.1 patent gazette]|

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2020-09-24| B09A| Decision: intention to grant|

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2020-12-15| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 11/12/2014, OBSERVADAS AS CONDICOES LEGAIS. |

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2021-04-13| B16C| Correction of notification of the grant|Free format text: REF. RPI 2606 DE 15/12/2020 QUANTO AO RELATORIO DESCRITIVO. |

优先权:

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申请号 | 申请日 | 专利标题

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US201361915514P| true| 2013-12-13|2013-12-13|

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US61/915,514|2013-12-13|

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US201462009923P| true| 2014-06-10|2014-06-10|

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US62/009,923|2014-06-10|

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PCT/US2014/069654|WO2015089246A1|2013-12-13|2014-12-11|Fragrance compositions|

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